1991
DOI: 10.1295/polymj.23.1069
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Structures and Optical Properties of Resins Containing Several Carboxylic Acids Neutralized with Barium Ion

Abstract: ABSTRACT:Monomer composites containing an aromatic carbozylic acid and methacry1ic acid (or acrylic acid) partially neutralized with a barium compound showed good solubility in chlorostyrene at high barium ion concentrations, unlike composites containing only one carboxylic acid. The improved solubility was due to the presence of an ionic crosslink composed of the aromatic carboxylate ion and methacrylate (acrylate) ion bridged with a barium ion, which provided an effective structure for depressing the growth … Show more

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“…The authors attributed the lower levels of delignification to Ba +2Promoting the coagulation of kraft lignin. In addition, Ba +2ions.are reported to form "ionic cross-linkages" between carboxylic anions [15]; such ionic crosslinkages could increase the hydrodynamic volume of oxidized lignin [7] via coagulation and decrease the solubility of the lignin in aqueous solutions.…”
Section: Literature Observations On Lignin Solubility and Extractionmentioning
confidence: 99%
“…The authors attributed the lower levels of delignification to Ba +2Promoting the coagulation of kraft lignin. In addition, Ba +2ions.are reported to form "ionic cross-linkages" between carboxylic anions [15]; such ionic crosslinkages could increase the hydrodynamic volume of oxidized lignin [7] via coagulation and decrease the solubility of the lignin in aqueous solutions.…”
Section: Literature Observations On Lignin Solubility and Extractionmentioning
confidence: 99%