The chromate nanoparticles such as CoCr2O4, NiCr2O4, CuCr2O4, and ZnCr2O4 were prepared by a modified sol–gel
method. The structural and morphological properties of the chromate
nanoparticles were characterized by X-ray diffraction (XRD) and a
scanning electron microscope (SEM). The catalytic effects of chromates
on the thermal decomposition of fine ammonium perchlorate (FAP) and
hexanitrohexaazaisowurtzitane (CL-20) were studied by the TG-DTG measurements.
Results show that the addition of CoCr2O4, NiCr2O4, CuCr2O4, and ZnCr2O4 nanoparticles makes the activation energies
for the thermal decomposition of FAP decrease by 93.9, 94.0, 83.1,
and 67.0 kJ·mol–1, and the thermal decomposition
temperatures decrease by 45.0, 24.9, 57.7, and 38.8 K respectively.
On the other hand, a similar trend exists in the case of the thermal
decomposition of CL-20. Therefore, the addition of nanochromates shows
high catalytic efficiency on the thermal decomposition of both FAP
and CL-20 components, which would be beneficial to promote the burning
rate of propellants containing FAP and CL-20 components.