Studies on extraction of Cu(II), Ga(III), In(III) and Tl(III) with 1-phenyl-3-methyl-4-benzoylpyrazol-5-oneSeparation and spectrophotometric determination of copper and gallium

Mirza, Μ. Y.

doi:10.1016/0039-9140(78)80172-6

Cited by 28 publications

(4 citation statements)

References 10 publications

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“…Among organophosphorus ligands, di(2-ethylhexyl)phosphoric acid (D2EHPA) is one of the most frequently used compound [14, 15 -19]. Other nitrogenous reagents such as amines [20,21] or oximes [22,23] as well as other b -diketones ligands like 4-acylpyrazol-5ones and 4-acylisoxazol-5-ones [11,12] have been also investigated for the extraction of copper(II) from chloride, nitrate and sulfate solutions.…”

Section: Introductionmentioning

confidence: 99%

Synergistic Effect of Sodium Dodecyl Sulfate Micelles on Copper(II) Extraction from Saline Sulfate Medium with Some Ortho-Hydroxy-Schiff Base Chelating Extractants

Youcef¹,

Benabdallah²,

Reffas³

2013

Tenside Surfactants Detergents

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The present study investigates the synergistic effect of the anionic surfactant sodium dodecyl sulfate micelles (SDS)o nt he solvent extraction of copper(II)f rom saline sulfate medium by some ortho-hydroxyS chiff base extracting agents (HL) in chloroform at (25 ±2) 8 C. The Schiff base extractants used are Nsalicylideneaniline (HSA), N-(2-hydroxy-1-naphthalidene)aniline (HNA) and N-(2-hydroxy-1-naphthalidene)naphthylamine (HNN). In the absence of SDS, the estimated extraction constantso ft he three ligands revealed that the extraction efficiency increased in the order HNNH NA >H SA.Asynergistic extraction mechanism of copper(II)with ortho-hydroxy Schiff bases in the presence of the surfactant has been proposed.

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Section: Introductionmentioning

confidence: 99%

Synergistic Effect of Sodium Dodecyl Sulfate Micelles on Copper(II) Extraction from Saline Sulfate Medium with Some Ortho-Hydroxy-Schiff Base Chelating Extractants

Youcef¹,

Benabdallah²,

Reffas³

2013

Tenside Surfactants Detergents

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“…Methyl isobutyl ketone (MIBK) [6], carboxylic acids [7,8], amines [9][10][11], quinolines [12] and β-diketones [13] have also been applied for this goal. In addition to these compounds, hydroxamic acids [14] are a class of versatile extractants which have significant importance as analytical tools for the separation and quantitative determination of a large number of metal ions [15,16].…”

Section: Introductionmentioning

confidence: 99%

Selective Extraction of Ga(III) with <i>p-t</i>-Butylcalix[4]arene Tetrahydroxamic Acid

Chetry

Adhikari

Morisada

et al. 2015

SERDJ

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Solvent extraction behavior of p-tert-butylcalix [4]arene tetrahydroxamic acid towards some trivalent as well as divalent cations was studied. The extraction selectivity of some cations followed the order Ga(III) > In(III) > Fe(III) > Cu(II) >> Zn(II), Ni(II). Since the extraction reagent exhibited high selectivity for Ga (III) and In(III), the detailed extraction behavior for Ga(III) and In(III) was investigated by slope analysis, the continuous variation method, and by loading tests. It was confirmed that both metals formed 1:1 complexes with the extraction reagent. Since the pK a values for hydroxamic acids are 8-9, there was 6-7 units of pH shift in the metal extraction caused by the complexation of Ga(III) indicating that this ligand served as an excellent reagent for selective extraction of Ga(III). The coordination site of the ligand for both metals was qualitatively investigated by IR spectra before and after metal loading on the ligand. The loaded Ga(III) was quantitatively stripped by using dilute acidic solutions and the ligand was regenerated.

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“…Among the various systems, organophosphorus extractants are most often used [2][3][4][5][6]. Methyl isobutyl ketone (MIBK) [7], carboxylic acids [8,9], amines or ammonium salts [10][11][12], quinolines [13,14], and b-diketones [15] have also found their applications for this goal.…”

Section: Introductionmentioning

confidence: 99%

An extraction study of gallium, indium, and zinc with mixtures of sec-octylphenoxyacetic acid and primary amine N1923

Jia

et al. 2011

Separation and Purification Technology

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Studies on extraction of Cu(II), Ga(III), In(III) and Tl(III) with 1-phenyl-3-methyl-4-benzoylpyrazol-5-oneSeparation and spectrophotometric determination of copper and gallium

Cited by 28 publications

References 10 publications

Synergistic Effect of Sodium Dodecyl Sulfate Micelles on Copper(II) Extraction from Saline Sulfate Medium with Some Ortho-Hydroxy-Schiff Base Chelating Extractants

Synergistic Effect of Sodium Dodecyl Sulfate Micelles on Copper(II) Extraction from Saline Sulfate Medium with Some Ortho-Hydroxy-Schiff Base Chelating Extractants

Selective Extraction of Ga(III) with <i>p-t</i>-Butylcalix[4]arene Tetrahydroxamic Acid

An extraction study of gallium, indium, and zinc with mixtures of sec-octylphenoxyacetic acid and primary amine N1923

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