Studies on the Mechanism of the Electrolytic Formation of Perchlorate

Sugino, Kiichiro; Aoyagi, Shigeru

doi:10.1149/1.2430258

Cited by 17 publications

(11 citation statements)

References 2 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The overvoltage of the upper Tafel curves decreases with increased perchloric acid concentration at a given current density. Similar results have been obtained from a sodium chlorate electrolysis on a platinum electrode [15].…”

Section: Mechanism For Perchlorate Formationsupporting

confidence: 86%

See 1 more Smart Citation

Mechanism of anodic oxidation of chlorate to perchlorate on platinum electrodes

Janssen

Heyden

1995

J Appl Electrochem

View full text Add to dashboard Cite

The kinetics and mechanism of the anodic oxidation of chlorate to perchlorate on platinum electrodes have been investigated. The current efficiency for perchlorate formation and the electrode potential have been determined as a function of current density for various solution compositions, flow rates and pHs at 50 ° C. The results have been compared with theoretical relations between the ratio of the current efficiencies for perchlorate and oxygen formation, the electrode potential, the concentration of chlorate at the electrode surface and the current density for various possible mechanisms. It is concluded that the formation of an adsorbed hydroxyl radical is the first step in the overall electrode reaction. The mechanism proposed for the C104 perchlorate and oxygen formation is:The ratio between the current efficiency for perchlorate and that for oxygen formation is determined by the rate of the electrode reaction involving C103 and that for the combination reaction of (OH)a d. List of symbols

show abstract

Section: Mechanism For Perchlorate Formationsupporting

confidence: 86%

“…The potential of the inflection point is much higher for perchlorate solution than for a chlorate solution [15] and the current density for oxygen evolution at the inflection potential is much higher for a perchlorate solution than for a chlorate solution (Fig. 3).…”

Section: Mechanism For Perchlorate Formationmentioning

confidence: 99%

Mechanism of anodic oxidation of chlorate to perchlorate on platinum electrodes

Janssen

Heyden

1995

J Appl Electrochem

View full text Add to dashboard Cite

show abstract

“…Although several mechanisms have been proposed [3,5,7], two mechanisms for the anodic oxidation of chlorate are worth discussion. According to the first mechanism the chlorate reacts with discharged oxygen resulting from the oxidation of water and chemisorbed at the electrode surface [14].…”

Section: Perchlorate Formation Reactions and Mechanismsmentioning

confidence: 99%

“…fact which is explained [3] due to the discharge potential for oxygen at platinum being lower in alkaline than in acid solutions. Furthermore, oxidizing power is lower in alkaline than in neutral or acid solutions.…”

Section: September 2009mentioning

confidence: 99%

“…Schumacher [2] reported other methods for manufacturing of perchlorates from different raw materials. The mechanism, kinetic aspects and electrode materials for perchlorate formation were dealt with within the literature [3][4][5][6][7]. After understanding the mechanism of perchlorate formation, attempts were made to study the different anode materials like platinum [8], and lead dioxide anode [6].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Optimization of the process parameters for an electrochemical preparation of strontium perchlorate

Vasudevan

2009

Korean J. Chem. Eng.

View full text Add to dashboard Cite

The electrochemical preparation of strontium perchlorate, Sr(ClO 4 ) 2 , from strontium chlorate employing platinum anode and a rotating stainless steel cathode is described. The effect of electrolyte concentration, current density, pH and temperature of the electrolyte and cathode rotation on current efficiency for the preparation of strontium perchlorate was studied. A maximum current efficiency of 42% was achieved corresponding to an energy consumption of 6.1 kWh. kg −1 .

show abstract

Perchloric Acid and Perchlorates

Mendiratta¹,

Dotson²,

Brooker³

2000

Kirk-Othmer Encyclopedia of Chemical Technology

View full text Add to dashboard Cite

Perchlorates are chlorine oxyanions in which the chlorine is present in its highest oxidation state ( \documentclass{article}\pagestyle{empty}\begin{document}${{\rm{+}}7}$\end{document} ). The most outstanding property of the perchlorates, which are more stable than other chlorine oxyanions, is their oxidizing ability. Most cations form perchlorate compounds. Commercially, one of the most important compounds of this class is ammonium perchlorate, used as an oxidizer in propellant formulations for solid rocket fuel. Perchlorates are also used in explosives and pyrotechnics, in dry batteries, and in oxygen‐generation systems. Commercial perchlorates are prepared by electrochemical oxidation. Perchloric acid, commercially available as a 72% aqueous solution, is one of the strongest of the mineral acids. Properties, manufacturing, and uses of these compounds are described.

show abstract

Studies on the Mechanism of the Electrolytic Formation of Perchlorate

Cited by 17 publications

References 2 publications

Mechanism of anodic oxidation of chlorate to perchlorate on platinum electrodes

Mechanism of anodic oxidation of chlorate to perchlorate on platinum electrodes

Optimization of the process parameters for an electrochemical preparation of strontium perchlorate

Perchloric Acid and Perchlorates

Contact Info

Product

Resources

About