It has been found that high-order deformation (e.g. β 6 ) can have important effects on the structures of superheavy nuclei. In the present work, we investigate octupole deformation effects on superheavy nuclei with an improved potential-energy-surface (PES) calculation by including reflection-asymmetric deformations in a space of (β 2 , β 3 , β 4 , β 5 ). The calculations give various deformations including highly deformed (β 2 ≈ 0.4) and superdeformed (β 2 ≈ 0.7) shapes. The octupole-deformation degree of freedom mainly affects the fission barrier beyond the second minimum of PES. Experimentally, octupole correlation manifests itself in atomic nuclei usually with enhanced E1 transitions connecting interleaved positive and negative-parity bands, which is similar to the rotational bands observed in reflectionasymmetric molecules [1]. Such correlation originates from the coupling of a pair of single-particle orbitals close to the Fermi Surface and having ΔN = 1, Δl = 3 and Δ j = 3. superdeformed minima are soft with respect to octupole deformations in A∼40, A∼150 and A∼190 mass regions [6][7][8]. This is because the single-particle spectrum at superdeformations favors octupole excitations due to the presence of intruder states [2]. Experiments have identified some octupolevibrational states and strong E1 transitions which are expected to connect these vibrational levels to the lowest SD band [7][8][9][10].With the development of the radioactive beam facility, heavy-ion accelerator and highly-effective detector systems [11,12], great progress has been made recently in nuclear physics including the synthesis of superheavy nuclei [13][14][15]. The deformations of superheavy nuclei are interesting. Superdeformed prolate [16][17][18] and superdeformed oblate [19] shapes have been predicted. In our previous works [20,21], we discussed the β 6 effects in superheavy nuclei [20] and the β 3 effects on high-K states at the second well of actinide nuclei [21]. In the present paper, using an improved potentialenergy-surface (PES) with the inclusion of reflectionasymmetric β 3 and β 5 deformations, we systematically calculate 248−264