2010
DOI: 10.1016/j.matchemphys.2010.02.063
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Study of phosphonate addition and hydrodynamic conditions on ordinary steel corrosion inhibition in simulated cooling water

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Cited by 98 publications
(30 citation statements)
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“…high frequency (HF), the first semicircle may be devoted to the adsorbed specie, whereas the second one is the response of a combination of R ct and constant phase element (CPE). At low frequency (LF), the obtained loop is generally assigned to a slow transport process like diffusion [41,42]. However, the Warburg impedance is introduced because it reflects the diffusion process of dissolved oxygen from the bulk solution to the electrode surface and/or the diffusion process of soluble zinc or copper species in the reverse sense.…”
Section: Electrochemical Impedance Spectroscopymentioning
confidence: 99%
“…high frequency (HF), the first semicircle may be devoted to the adsorbed specie, whereas the second one is the response of a combination of R ct and constant phase element (CPE). At low frequency (LF), the obtained loop is generally assigned to a slow transport process like diffusion [41,42]. However, the Warburg impedance is introduced because it reflects the diffusion process of dissolved oxygen from the bulk solution to the electrode surface and/or the diffusion process of soluble zinc or copper species in the reverse sense.…”
Section: Electrochemical Impedance Spectroscopymentioning
confidence: 99%
“…So, the water used as a thermal fluid in cooling circuits usually leads to three problems, namely, corrosion, scaling, and microorganism development. These phenomena are the source of a loss of the metallic material, a decrease of the thermal efficiency of the circuit, and the proliferation of microorganisms in the water, respectively, (Touir et al 2010;Srisuwan et al 2008). Indeed, iron is the principal redox-active metal in the metabolic processes of essentially all living organisms.…”
Section: Introductionmentioning
confidence: 99%
“…At high frequencies the size of the capacitive loop increases with the concentration. This is attributed to the formation of an inhibitor film with a barrier effect against the aggressive ions [35]. At low frequencies, the addition of inhibitors lead to an increase in the charge-transfer resistance (Rct) value (diameter of the loop between high and low frequency) which has a non-monotonous variation in relation to the inhibitor content.…”
Section: Electrochemical Impedance Spectroscopymentioning
confidence: 99%