Based on strain-induced grain refinement, a novel surface mechanical attrition treatment
(SMAT) technique has been developed to synthesize a nanostructured surface layer on metallic
materials in order to upgrade their overall properties and performance without changing their
chemical compositions. In recent several years, the microstructures and properties of surface layer
were systematically investigated in various SMAT metals and alloys, including b.c.c., f.c.c. and h.c.p.
crystal structures. Different grain refinement approaches and nanocrystalline formation mechanisms
were identified in these deformed materials, involving dislocation activities, mechanical twinning and
interaction of dislocations with mechanical twins. The properties of the surface layer were measured
by means of hardness, tensile, fatigue and wear tests. The enhanced properties of the surface layer are
mainly attributed to the strain-induced grain refinement. In this work, we reviewed the
microstructures and properties of surface layer in the SMAT materials.