2009
DOI: 10.1016/j.jcrysgro.2009.02.022
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Study of the thermal decomposition of “captured” intermediates in the CVD of ZnO from DEZ and H2O by TGA–DTA and quadrupole mass spectroscopy

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Cited by 8 publications
(3 citation statements)
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“…1 that significant MeCp 2 Mg to DEZ ratio exceeding 10 is required to achieve the alloy Mg 0.40 Zn 0.60 O. We attribute the requirement for high ratios to better pyrolysis [39,40] of DEZ compared with MeCp 2 Mg at growth temperatures and especially to site competition between cationic species for oxygen. While we observe that the crystallization process is surface-reaction controlled because copious and linearly varying magnesium supply does not result in a commensurate linear progression of magnesium incorporation in the crystal; the effects of site competition are exacerbated for solutions of 10/1 MeCp 2 Mg/DEZ containing either donor or acceptor cationic species also shown in Fig.…”
Section: Resultsmentioning
confidence: 92%
“…1 that significant MeCp 2 Mg to DEZ ratio exceeding 10 is required to achieve the alloy Mg 0.40 Zn 0.60 O. We attribute the requirement for high ratios to better pyrolysis [39,40] of DEZ compared with MeCp 2 Mg at growth temperatures and especially to site competition between cationic species for oxygen. While we observe that the crystallization process is surface-reaction controlled because copious and linearly varying magnesium supply does not result in a commensurate linear progression of magnesium incorporation in the crystal; the effects of site competition are exacerbated for solutions of 10/1 MeCp 2 Mg/DEZ containing either donor or acceptor cationic species also shown in Fig.…”
Section: Resultsmentioning
confidence: 92%
“…For both films, a loss of weight is observed between 50 o C and 130 o C related to absorbed water removal. Pronounced weight loss between 130 o C and 180 o C is related to removal of adsorbed crystal water molecules (19)(20)(21)(22). Beyond 180 o C a weight change is observed that is more pronounced in the sample obtained with PEG in the bath.…”
Section: Resultsmentioning
confidence: 95%
“…Recently, delafossite-based materials extensively explored, particularly after CuAlO 2 was invented, which was excellent p-type transparent conducting oxide (TCO) material. [9][10][11][12][13][14] Copper-related delafossites materials have interesting properties. However, the electrochemical ability of delafossite CuAlO 2 has not been reported extensively.…”
mentioning
confidence: 99%