“…Through precise molecular engineering, AIE-active luminogens (AIE-gens) can be introduced into the polymer structures; the resulting AIE-active samples display the combined advantages of a polymer and AIE-gen, thus expanding the application scope of AIE materials. − AIE-active polymers exhibit the merits of structural diversity, high processability, heat resistance, and excellent mechanical properties compared with AIE small molecules. , However, most AIE-gens usually contain aromatic groups and conjugated subunits as chromophore centers, which results in several disadvantages, such as a complicated structure, expensive synthesis, toxic starting materials, and cytotoxicity. − With the advent of wearable monitoring devices in day-to-day life and brand clothing anticounterfeiting, the development of fluorescent fabrics has seen rapid growth. Over the past decade, fluorescent fibers have been fabricated using various novel techniques, such as melt spinning, electrospinning, and surface coating via a simple physical combination of polymer matrices and luminogens. − However, these fluorescence fibers have displayed poor fluorescence intensity and durability. Besides, the in situ preparation of arbitrary fluorescent patterns by traditional methods still remains a challenge.…”