Study on Crystal Growth of Tobermorite Synthesized by Calcium Silicate Slag and Silica Fume

Abstract

In order to high-value utilize the secondary solid waste calcium silicate slag (CSS) generated in the process of the extraction of alumina from fly ash, in this paper, tobermorite was synthesized using CSS and silica fume (SF) at different hydrothermal synthesis times. The hydrothermal synthesis was evaluated by means of XRD, SEM, EDS, and micropore analysis, and the results discussed. The results indicate that β-dicalcium silicate, the primary phase in the CSS, partially hydrates at the beginning of hydrothermal synthesis conditions to form mesh-like crystal C-S-H (calcium-rich) and calcium hydroxide. It then reacts with SF to form yarn-like crystal C-S-H (silicon-rich) and then furtherly grows into large flake-like crystal C-S-H (silicon-rich) at 3 h. When the synthesis time is 4 h, β-dicalcium silicate completely hydrates, and crystal C-S-H (calcium-rich) and calcium hydroxide further reacts with large flake-like crystal C-S-H (silicon-rich) to generate medium flake-like tobermorite. With the increase in time, the crystal of hydrothermal synthesis grows in the order of medium flake-like tobermorite, small flake-like tobermorite, strip flake-like tobermorite, fibrous-like tobermorite, and spindle-like tobermorite, and the APV, APD, and SSA show a trend of decreasing first, then increasing, and then decreasing. Meanwhile, strip flake-like tobermorite with a higher average pore volume (APV), average pore diameter (APD), and specific surface area (SSA) can be synthesized at 6 h.

Combined Potential of Quarry Waste Fines and Eggshells for the Hydrothermal Synthesis of Tobermorite at Varying Cement Content

“…The characterization of QWF and ESP, in this study, revealed that these waste materials contain the key components for tobermorite synthesis such as SiO 2 and CaO. Aside from construction applications, tobermorite has been gaining more attention in recent years due to its high utilization value in chemical and mechanical industries, its economy of materials, as well as its potential for environmental cleanup purposes [75,[78][79][80].…”

Combined Potential of Quarry Waste Fines and Eggshells for the Hydrothermal Synthesis of Tobermorite at Varying Cement Content

“…The characterization of QWF and ESP, in this study, revealed that these waste materials contain the key components for tobermorite synthesis such as SiO2 and CaO. Aside from construction applications, tobermorite has been gaining more attention in recent years due to its high utilization value in chemical and mechanical industries, its economy of materials, as well as its potential for environmental cleanup purposes [78,[81][82][83].…”