Study on electrochemical performance of carbon-coated LiFePO4 as cathode material for lithium ion batteries

Triwibowo, Joko; Priyono, Slamet; Purawiardi, Ibrahim; Lestariningsih, Titik; Ratri, Christin Rina

doi:10.1063/1.4958582

Cited by 11 publications

(8 citation statements)

References 11 publications

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“…Figure A shows the CV of BM PBA. At a scan rate of 0.1 mV s –1 , the set of iron redox peaks appears at 0.17/0.16 V (O1/R1) and 0.29/0.27 V (O2/R2), which are similar to those found in LiFePO 4 , 0.16/0.36 (O/R). , The electrochemical characteristics of our electrodes were investigated by increasing the scan rates from 0.1 to 5 mV s –1 . The following equation i = av b was utilized to study electrode kinetics, b values of 0.9/0.89 and 0.89/0.93 were found for the two sets of oxidation/reduction peaks as seen in Figure B. ,− This intercalation pseudocapacitative response is due to the small dimension and high surface area of the primary particles. , These two factors promote a facile Na-ion insertion/extraction mechanism and amplify the pseudocapacitive character of the battery electrode. , The Faradaic nature of this mechanism will be explored and supported by bulk-sensitive XAS.…”

Section: Resultssupporting

confidence: 66%

“…At a scan rate of 0.1 mV s −1 , the set of iron redox peaks appears at 0.17/0.16 V (O1/R1) and 0.29/0.27 V (O2/R2), which are similar to those found in LiFePO 4 , 0.16/0.36 (O/R). 24,25 The electrochemical characteristics of our electrodes were investigated by increasing the scan rates from 0.1 to 5 mV s −1 . The following equation i = av b was utilized to study electrode kinetics, b values of 0.9/0.89 and 0.89/0.93 were found for the two sets of oxidation/reduction peaks as seen in Figure 3B.…”

Section: ■ Introductionmentioning

confidence: 99%

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Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Lucero

Armitage

Yang

et al. 2023

ACS Appl. Mater. Interfaces

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Aqueous Na-ion batteries using Prussian blue materials have inherent advantages in safety, material sustainability, and economic cost. However, it is challenging to obtain long-term cycling stability because many redox reactions have poor intrinsic stability in water. Here, we demonstrate reversible Fe 2.4+ to Fe 3+ redox reaction of Prussian blue electrodes cycled in a 17 m NaClO 4 water-in-salt electrolyte. The cubic phase c-Na 1.17 Fe[Fe(CN) 6 ]•0.35H 2 O) derived from monoclinic Prussian blue (m-Na 1.88 Fe[Fe(CN) 6 ]•0.7H 2 O) through ball milling delivers excellent cycling stability of >18,000 cycles with >90% capacity retention at the 10C rate. The specific capacity is ∼75 and ∼67 mAh/g at 1C and 10C rates, respectively. Systematic characterizations including electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, and Xray absorption spectroscopy have verified the phase transition and iron oxidation state evolution, revealing the mechanism that enables the material's high rate and long durability as the battery cathode.

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Section: Resultssupporting

confidence: 66%

Section: ■ Introductionmentioning

confidence: 99%

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Lucero

Armitage

Yang

et al. 2023

ACS Appl. Mater. Interfaces

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“…Figure E also shows an incremental relationship between the electronegativity and the redox energy of the TMO, considering similar coordination numbers and oxidation states for the transition metal ions in the same row. Surprisingly, the μ c values possessed by LiCoO 2 (∼3.9 V vs Li/Li + ), LiMn 2 O 4 (∼4.0 V vs Li/Li + ), LiFePO 4 (∼3.4 V vs Li/Li + ), , and LiMnPO 4 (∼4.1 V vs Li/Li + ) , do not follow similar fashions. For the ease of comparison, we look into details that cause the significant differences in μ c between olivine LiFePO 4 and LiMnPO 4 .…”

Section: Origin Of Working Potential (V Cell)mentioning

confidence: 92%

Phosphate Polyanion Materials as High-Voltage Lithium-Ion Battery Cathode: A Review

et al. 2021

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Followed by decades of successful efforts in developing cathode materials for high specific capacity lithium-ion batteries, currently the attention is on developing a high-voltage battery (>5 V vs Li/Li+) with an aim to increase the energy density for their many fold advantages over conventional <4 V batteries. Among the various cathode materials, phosphate polyanion materials (LiMPO4, where M is a single metal or a combination of metals) showed promising candidacy given their high electrochemical potential (4.8–5 V vs Li/Li+), long cycle stability, low cost, and achieved specific capacity (∼165 mAh·g–1) near to its theoretical limit (170 mAh·g–1). In this review, factors affecting the electrochemical potential of the cathode materials are reviewed and discussed. Techniques to improve the electrical and ionic conductivities of phosphate polyanion cathodes, namely, surface coating, particle size reduction, doping, and morphology engineering, are also discussed. A processing–property correlation in phosphate polyanion materials is also undertaken to understand relative merits and drawbacks of diverse processing techniques to deliver a material with targeted functionality. Strategies required for high-voltage phosphate polyanion cathode materials are envisioned, which are expected to deliver lithium-ion battery cathodes with higher working potential and gravimetric specific capacity.

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“…Riset dan pengembangan baterai lithium-ion yang dilakukan di Indonesia umumnya menitikberatkan pada pembuatan material-material bahan aktif untuk katoda, anoda dan elektrolit. Bahan-bahan aktif untuk katoda yang dikembangkan sendiri adalah LiFePO4 6,7,8,9) dan LiMnPO4 10) . Sementara itu, bahan aktif untuk anoda yang dikembangkan adalah Li4Ti5O12 11,12,13) , sedangkan bahan elektrolit yang dikembangkan adalah LiBOB 14,15,16,17) .…”

Section: Pendahuluanunclassified

POTENSI RISET DAN PENGEMBANGAN FePO4 DARI BAHAN BAKU LOKAL Fe2O3 DI INDONESIA

Purawiardi¹

2023

Majalah Ilmiah Pengkajian Industri

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Riset dan pengembangan baterai lithium mulai banyak dilakukan di Indonesia sejak awal dekade 2000-an. Diantara salah satu material yang dikembangkan adalah bahan aktif katoda LiFePO4,dengan harapan bahwa seluruh bahan baku pembuatan LiFePO4 diperoleh dari sumberdaya lokal. Sumber-sumber bahan baku LiFePO4 sendiri adalah LiOH atau LiOH.H2O atau Li2CO3 atau CH3COOLi sebagai sumber Li, Fe2O3 sebagai sumber Fe, dan H3PO4 sebagai sumber PO43-. Diantara berbagai sumber bahan baku tersebut, Fe2O3 dan H3PO4 dapat diperoleh dari dalam negeri, namun sumber lithium masih harus impor. Oleh sebab itu, produksi LiFePO4 kedepannya tidak dapat 100% menggunakan bahan baku lokal. Namun, terdapat satu cara yang dapat dilakukan agar menggunakan 100% bahan baku lokal, yaitu pengembangan FePO4. FePO4 ini nantinya berpotensi untuk diproduksi dan diekspor sebagai bahan baku pembuatan LiFePO4. Disamping itu, FePO4 juga memiliki nilai tambah lain sebagai bahan pelapis pencegah oksidasi pada permukaan logam. Oleh sebab itu, material ini cukup strategis untuk dikembangkan di Indonesia.

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Study on electrochemical performance of carbon-coated LiFePO4 as cathode material for lithium ion batteries

Cited by 11 publications

References 11 publications

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Phosphate Polyanion Materials as High-Voltage Lithium-Ion Battery Cathode: A Review

POTENSI RISET DAN PENGEMBANGAN FePO4 DARI BAHAN BAKU LOKAL Fe2O3 DI INDONESIA

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Study on electrochemical performance of carbon-coated LiFePO4 as cathode material for lithium ion batteries

Cited by 11 publications

References 11 publications

Ball Milling-Enabled Fe2.4+ to Fe3+ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Ball Milling-Enabled Fe2.4+ to Fe3+ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Phosphate Polyanion Materials as High-Voltage Lithium-Ion Battery Cathode: A Review

POTENSI RISET DAN PENGEMBANGAN FePO4 DARI BAHAN BAKU LOKAL Fe2O3 DI INDONESIA

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Product

Resources

About

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries