Study on NH4I composition effect in agar–agar-based biopolymer electrolyte

Selvalakshmi, S.; Mathavan, T.; Selvasekarapandian, S.; Premalatha, M.

doi:10.1007/s11581-016-1952-2

Cited by 50 publications

(16 citation statements)

References 19 publications

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“…On further increases of MgCl 2 salt concentration to 0.55 M.wt% the polymer electrolytes crystallinity is increases. Amorphous phase has low energy barrier, then the ions easy move through the polymer matrix [14]. The biopolymer electrolyte 1.0 g GG with 0.5 M.wt% of MgCl 2 has a low intensity much broader peak which conforms that has more amorphous nature.…”

Section: Preparation Of Cathodementioning

confidence: 87%

Biopolymer Electrolyte Based on Gellan Gum With Magnesium Chloride for Magnesium Battery

Krishna¹,

Rm²,

Monisha³

2021

Preprint

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Eco-Friendly, non-toxic and biodegradable natural biopolymer electrolyte, Gellan Gum with Magnesium Chloride has been prepared by solution casting technique. The prepared biopolymer electrolyte has been characterized by XRD, FTIR, DSC and AC impedance analysis techniques. XRD study is used to analyze amorphous nature/crystalline nature of the polymer electrolyte. Complex formation between Gellan Gum and magnesium chloride salt has been studied by FTIR technique. The glass transition temperature (Tg) of the polymer electrolytes are obtained by DSC measurement. The highest ionic conductivity 2.91×10− 2 Scm− 1 has been obtained for electrolyte of 1.0 g Gellan Gum with 0.5 M.wt% MgCl2 from AC impedance analysis at room temperature. Transference number 0.97 has been obtained by Wagner’s polarization method for high conducting sample. The Mg2+ cationic transport number 0.35 has been found by Evan’s method for high conducting sample. Magnesium ion conducting battery has been constructed using the high conducting polymer electrolyte. Its open circuit voltage 2.39 V and the battery discharge characteristics are studied.

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Section: Preparation Of Cathodementioning

confidence: 87%

Biopolymer Electrolyte Based on Gellan Gum With Magnesium Chloride for Magnesium Battery

Krishna¹,

Rm²,

Monisha³

2021

Preprint

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“…The electrochemical performance is an important parameter of the energy storage system. The electrochemical window stability of the biopolymer films was examined by linear sweep voltammetry (LSV) [31,32]. The biopolymer films were sandwich between the two stainless steel blocking electrodes with scan rate 10 mV s −1 and voltage range from −3 to +3 V. Figure 2 shows the linear sweep voltammetry curve at room temperature.…”

Section: Electrochemical Performancementioning

confidence: 99%

Investigation of Magnesium Ion and Cellulose Acetate-Based Conducting Biopolymers: Electrical and Ion Transport Properties

Sadiq

Raza

Zulfequar

et al. 2021

Springer Proceedings in Materials

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The conducting biopolymer based on cellulose acetate with various concentration of magnesium perchlorate were prepared by standard solution cast technique. The electrical properties and electrochemical performance of as-prepared biopolymer films were investigated by electrochemical impedance technique. The maximum ionic conductivity of biopolymer electrolytes films approximately of order 10 -4 S/cm at 30 °C. The voltage stability limit of biopolymer electrolyte films was examined by linear voltammetry and cyclic voltammetry for use in energy storage device applications. The highest electrochemical window 4.5 V is achieved at 50% of Mg (ClO 4 ) 2 . IntroductionIn this current time, a lot of energy is required to full fill the need of modern lifestyle and industry. So, the entire population of the world depends on fossil fuels. There are many disadvantages of the fossil fuels like limited resources, non-renewable, and producing massive air pollution [1,2]. All these factors motivate the research community to find an alternative resource in terms of renewability and sustainability. There are many renewable energy sources like fuel cells, wind, and solar cells [3,4]. The new and emerging science of polymer electrolytes becoming a promising candidate to store energy and replace non-renewable resources. Polymer electrolyte extensively gets used in many applications like energy storage, supercapacitor, solar

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“…On the basis of the plateau region in this graph, the trend of the σ dc values for all of the obtained GPE samples agreed well with the σ values that were determined from R b of the Cole-Cole plot. The increase in the charge-carrier concentration was attributed to the increase in the ionic mobility within the GPE sample, which could lead to an increase in σ dc : 35,36 log…”

Section: Frequency-dependent σ Studiesmentioning

confidence: 99%

Polyacrylonitrile–poly(1‐vinyl pyrrolidone‐co‐vinyl acetate) blend based gel polymer electrolytes incorporated with sodium iodide salt for dye‐sensitized solar cell applications

Saidi

Omar

et al. 2019

J of Applied Polymer Sci

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New gel polymer electrolytes (GPEs) were prepared via the blending of a polyacrylonitrile polymer and a poly(1‐vinyl pyrrolidone‐co‐vinyl acetate) copolymer. The sodium iodide (NaI) salt concentration was varied for each GPE sample. From ionic conductivity (σ) studies, we observed that the sample with a 40 wt % NaI salt content (N40) showed the highest σ of 3.54 × 10−3 ± 0.05 S/cm at room temperature, and all of the GPE samples obeyed Arrhenius behavior. The dielectric properties of the GPE samples were also analyzed to study the electrical polarization of the materials. The developed GPE samples were also characterized with X‐ray diffraction and Fourier transform infrared spectroscopy. We also then used the developed GPE samples for the fabrication of dye‐sensitized solar cells by sandwiching them between a photoanode and Pt counter electrode for photovoltaic studies. The highest photovoltaic performance was achieved by N40, with an efficiency of 3.04%. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47810.

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Study on NH4I composition effect in agar–agar-based biopolymer electrolyte

Cited by 50 publications

References 19 publications

Biopolymer Electrolyte Based on Gellan Gum With Magnesium Chloride for Magnesium Battery

Biopolymer Electrolyte Based on Gellan Gum With Magnesium Chloride for Magnesium Battery

Investigation of Magnesium Ion and Cellulose Acetate-Based Conducting Biopolymers: Electrical and Ion Transport Properties

Polyacrylonitrile–poly(1‐vinyl pyrrolidone‐co‐vinyl acetate) blend based gel polymer electrolytes incorporated with sodium iodide salt for dye‐sensitized solar cell applications

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