2010
DOI: 10.1016/j.memsci.2010.06.002
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Study on phosphorylated Zr-doped hybrid silicas/PSF composite membranes for treatment of wastewater containing oil

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Cited by 25 publications
(7 citation statements)
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“…The porosity existed in MIP play an important role for above results. [18,19] Due to the sufficient self-assembly between SSO and functional monomers, the quantities of free loci in MIP network decreased dramatically compared with that of NMIP, [20] which meant interaction, among polymer chains and between polymer and solvent, was decreased, and the phase separation difficulty decreased correspondingly. Owing to the phase separation showed a negative correlation with the interaction, and the strong interaction meant a more serous structure collapse, [16] the pores formed by the pore-foaming agent, chloroform, collapsed and jammed badly in NMIP than that of MIP during drying.…”
Section: Determination Of Adsorption Isothermmentioning
confidence: 99%
“…The porosity existed in MIP play an important role for above results. [18,19] Due to the sufficient self-assembly between SSO and functional monomers, the quantities of free loci in MIP network decreased dramatically compared with that of NMIP, [20] which meant interaction, among polymer chains and between polymer and solvent, was decreased, and the phase separation difficulty decreased correspondingly. Owing to the phase separation showed a negative correlation with the interaction, and the strong interaction meant a more serous structure collapse, [16] the pores formed by the pore-foaming agent, chloroform, collapsed and jammed badly in NMIP than that of MIP during drying.…”
Section: Determination Of Adsorption Isothermmentioning
confidence: 99%
“…With changing regulations and limited availability of fresh water, treatments for water produced by oil operations and oily wastewaters have gained increasing interest . Conventional approaches for treating oily wastewaters have included de‐emulsification, gravity separation and skimming, coagulation, dissolved air flotation, and flocculation . The small quantity of oil remaining in the water after the conventional methods must be reduced to an acceptable limit before the water can be discharged into seas or rivers.…”
Section: Introductionmentioning
confidence: 99%
“…[32][33][34] Conventional approaches for treating oily wastewaters have included de-emulsification, gravity separation and skimming, coagulation, dissolved air flotation, and flocculation. [35][36][37] The small quantity of oil remaining in the water after the conventional methods must be reduced to an acceptable limit before the water can be discharged into seas or rivers. Membrane separation can effectively meet those standards.…”
Section: Introductionmentioning
confidence: 99%
“…STSNs/PSF composite membranes were prepared by phase inversion methods [11]. Firstly, STSN were added to DMAC in a 500ml flask under stirring at 60°C.…”
Section: Preparation Of Stsns/psf Composite Membranesmentioning
confidence: 99%
“…Though the capability of polymer membrane can be enhanced by adding inorganic oxide particles mentioned above, further enhancement is limited because there are few Lewis acid sites and hydroxide radicals on the surface of these stoichiometric monocomponent inorganic oxide particles. To solve the above problem, Zhang et al prepared phosphorylated Zr-doped hybrid silica (SZP)/PSF composite membranes [11] and sulfated Y-doped zirconia (SZY)/PSF composite membranes [12], evidently improving the hydrophilic property and anti-fouling ability of PSF membranes. It is because that on the one hand, these nonstoichiometric inorganic oxide particles have Lewis acid sites, point defects and lots of exposed hydroxide radicals on the surface; on the other hand, acidified particles can increase the number of hydroxide radicals on the particle surface, which can form a lot of hydrogen bonds with molecules and further enhance the hydrophilicity of the particles.…”
Section: Introductionmentioning
confidence: 99%