Study on the Influence of Pressure Reduction and Chemical Injection on Hydrate Decomposition

Abstract

This study simulated seabed high pressure and low temperature conditions to synthesize natural gas hydrates, multi-stage depressurization mode mining hydrates as the blank group, and then carried out experimental research on the decomposition and mining efficiency of hydrates by depressurization and injection of different alcohols, inorganic salts, and different chemical agent concentrations. According to the experimental results, the chemical agent with the best decomposition efficiency is preferred; the results show that: the depressurization and injection of a certain mass concentration of chemical agents to exploit natural gas hydrate is more effective than pure depressurization to increase the instantaneous gas production rate. This is because depressurization combined with chemical injection can destroy the hydrate phase balance while effectively reducing the energy required for hydrate decomposition, thereby greatly improving the hydrate decomposition efficiency. Among them, depressurization and injection of 30% ethylene glycol has the best performance in alcohols; the decomposition efficiency is increased by 52.0%, and the mining efficiency is increased by 68.2% within 2 h. Depressurization and injection of 15% calcium chloride has the best performance in inorganic salts; the decomposition efficiency is increased by 46.3%, and the mining efficiency is increased by 61.1% within 2 h. In the actual mining process, the appropriate concentration of chemical agents should be used to avoid polluting the environment.

Production Characteristics of Water-Saturated Methane Hydrates under Different Thermodynamic Conditions

“…The essence of hydrate exploitation is to dissociate the hydrates, and the main methods include depressurization, − thermal stimulation, , chemical injection, , CO 2 replacement, − and a combination of these methods. − The depressurization method is considered to be the most economical way to exploit hydrates due to its simplicity and high energy efficiency. , China and Japan have verified the effectiveness of large-scale exploitation projects of marine hydrates in Shenhu Sea , and Otami Peninsula-Shima Peninsula, , respectively. In addition, it has been used by most researchers in the laboratory-scale simulation of the hydrate exploitation process.…”

“…The essence of hydrate exploitation is to dissociate the hydrates, 10 and the main methods include depressurization, 11−13 thermal stimulation, 14,15 chemical injection, 16,17 CO 2 replacement, 18−21 and a combination of these methods. 22−24 The depressurization method is considered to be the most economical way to exploit hydrates due to its simplicity and high energy efficiency.…”