The reservoir heterogeneity and unfavorable oil/gas mobility
ratio
lead to gas channeling and low CO2 sweep efficiency during
CO2 flooding in low-permeability reservoirs. A dispersed
particle gel (DPG) could migrate deep into the reservoir and coalesce,
which has the potential for CO2 gas channeling control.
In this work, a CO2-resistant bulk gel was prepared by
a cross-linking reaction of a copolymer with acid-resistant groups
and catechol–hexamethylenetetramine, which exhibited excellent
CO2 resistance. Subsequently, a CO2-resistant
dispersed particle gel (SCDPG) used in supercritical CO2 was successfully prepared from the CO2-resistant bulk
gel by a high-speed mechanical shearing method. Meanwhile, the coalescence
behavior of the SCDPG particles in supercritical CO2 was
systematically investigated from the microstructure, particle size,
ζ potential, and mechanical strength. The results showed that
the SCDPG particles were dispersed in the liquid phase as a single
particle. SCDPG had good dispersion stability during storage and injection.
In supercritical CO2, the dispersion stability of SCDPG
decreased, and the particles coalesced with each other to form aggregates
with a stereostructure instead of degradation. The SCDPG particles
maintained high mechanical strength, showing the long-term effectiveness
for gas channeling control during CO2 flooding. In addition,
the interparticle force of SCDPG particles was measured by an AFM
colloid probe based on the reservoir characteristics. The interparticle
force of SCDPG particles changed from repulsion to adhesion with increasing
salinity. At a salinity of 0.5 mol/L, the adhesion force increased
with the increase of temperature and the decrease of the pH value.
According to the type of intermolecular force, the adhesion force
originated from the hydrogen bond, π–π stacking,
and cation−π interaction. This work provides theoretical
support for the field application of the dispersed particle gel and
promotes the development of utilization of carbon dioxide in oilfields.