Study on the reaction mechanism between Pb3O4 and Si in stored silicon delay composition

Zhang, Han; Liu, Shang-Hao; Liu, Feng; Yan, Shilong; Li, Weiyi

doi:10.1007/s10973-017-6872-5

Cited by 9 publications

(2 citation statements)

References 10 publications

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“…Oxidants, after thermal decomposition, are the source of the oxygen, which is necessary for the combustion of a fuel. The reaction between components in this kind of compositions is not direct, as it comes in a solid-gas-solid system [3].…”

Section: Introductionmentioning

confidence: 99%

Study of gasless compositions used in time-delay elements

Gerlich

Wojewódka

2019

J Therm Anal Calorim

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This article presents the results of burn rate measurements conducted for a Fe/BaO 2 pyrotechnic delay composition. Compositions with an iron content between 15% (w/w) and 50% (w/w) yielded burn rates in the range of 4-36 mm s -1 . Mixtures containing more than 50% (w/w) iron could not be initiated by a powder fuse and are not suited for application as delay compositions. This study also presents a cost-efficient method for measuring linear combustion velocities and its application to the investigation of the Fe/BaO 2 composition. Thermogravimetric and XRD studies have revealed that the reactions between iron and barium peroxide take place in the solid phase, leading to the formation of varied spinels.

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Section: Introductionmentioning

confidence: 99%

Study of gasless compositions used in time-delay elements

Gerlich

Wojewódka

2019

J Therm Anal Calorim

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“…Among these β-PbO 2 it is a stable oxide and highly resistant to corrosion even in acidic environments. 10,11 Additionally, PbO 2 can convert to PbO by capturing electrons, contributing to the glass network formation with PbO 4 units and alternate with BiO 3 units. In contrast, Pb 2+ ions act as modifying ions and introduce structural imperfections in the glasses network.…”

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confidence: 99%

Dielectric Characteristics and A.C. Conductivity of Pb₃O₄-Bi₂O₃-B₂O₃:CuO Glass Ceramics with CuBi₂O₄ Crystal Phase: A Possible Electrode Material for Ionic Batteries

Bhadrarao,

Pavić,

Bafti

et al. 2023

ECS J. Solid State Sci. Technol.

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In this study, we investigated the dielectric properties of Pb3O4-Bi2O3-B2O3 (PBB) glass ceramics doped with varying CuO concentrations across wide frequency and temperature ranges. The structural analysis involved XRD, SEM, XPS, DTA, FT-IR, ESR, and OA spectra, revealed the presence of anisotropic CuBi2O4 ferroelectric crystal phases with the size of a few microns in these glass ceramics. The glass-ceramics containing a higher content of CuO indicated a maximal reduction of Cu2+ to Cu+ ions that inhabit network-forming sites. Dielectric properties, including ε′, M,′ M″, Z, and σ ac , were studied as functions of CuO content. ε′ and σ ac were observed to decrease, while impedance was found to increase with CuO up to 0.8 mol%. Observed dipolar effects were quantitatively discussed with the identification of probable dipoles. The study indicated decreased ionic and increased polaronic contributions to σ ac with a rise of CuO from 0.2 to 0.8 mol%. In conclusion, glass ceramics with low CuO content are suitable as solid electrolytes, while higher CuO content serves as electrode materials in solid-state batteries.

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Luminescence features of Ho³⁺, Er³⁺ and Tm³⁺ ions in red lead added non‐conventional antimony oxide glass system

Rao,

Sekhar,

Kumar

et al. 2023

Luminescence

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In this study, a glass system based on heavy metal oxides, namely Pb3O4‐Sb2O3‐SiO2, was prepared with Ho2O3, Er2O3, and Tm2O3 as dopants. The prepared glasses were characterized using XRD and IR studies. The luminescence efficiencies of the three rare earth ions viz., Ho3+, Er3+, and Tm3+ in the glass system were investigated, specifically focusing on green (Ho3+, Er3+), blue (Tm3+), and near‐infrared (NIR) emissions. The optical absorption (OA) and photoluminescence (PL) spectra of RE mixed glasses displayed strong bands in the visible and NIR regions, which were analyzed using J‐O theory. The J‐O coefficients (Ωλ) found to be in the order of Ω2 > Ω4 > Ω6 for all the three glasses. Notably, the Tm3+‐doped glasses exhibited the lowest Ω2 value, which was attributed to a larger degree of disorder in the glass network due to lower fractions of Sb5+ and Pb4+ ions that take part glass network forming. Such conclusion was arrived based on the IR studies. Furthermore, the quantitative analysis of PL spectra and decay curves indicated that SbHo and SbEr glasses are suitable for efficient green emission, while SbTm glass is a promising choice for blue laser emission.

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Study on the reaction mechanism between Pb3O4 and Si in stored silicon delay composition

Cited by 9 publications

References 10 publications

Study of gasless compositions used in time-delay elements

Study of gasless compositions used in time-delay elements

Dielectric Characteristics and A.C. Conductivity of Pb₃O₄-Bi₂O₃-B₂O₃:CuO Glass Ceramics with CuBi₂O₄ Crystal Phase: A Possible Electrode Material for Ionic Batteries

Luminescence features of Ho³⁺, Er³⁺ and Tm³⁺ ions in red lead added non‐conventional antimony oxide glass system

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Study on the reaction mechanism between Pb3O4 and Si in stored silicon delay composition

Cited by 9 publications

References 10 publications

Study of gasless compositions used in time-delay elements

Study of gasless compositions used in time-delay elements

Dielectric Characteristics and A.C. Conductivity of Pb3O4-Bi2O3-B2O3:CuO Glass Ceramics with CuBi2O4 Crystal Phase: A Possible Electrode Material for Ionic Batteries

Luminescence features of Ho3+, Er3+ and Tm3+ ions in red lead added non‐conventional antimony oxide glass system

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Dielectric Characteristics and A.C. Conductivity of Pb₃O₄-Bi₂O₃-B₂O₃:CuO Glass Ceramics with CuBi₂O₄ Crystal Phase: A Possible Electrode Material for Ionic Batteries

Luminescence features of Ho³⁺, Er³⁺ and Tm³⁺ ions in red lead added non‐conventional antimony oxide glass system