Substituent effect on the hydrolysis of chlorosilanes: quantum chemical and QSPR study

Tracking intramolecular energy redistribution dynamics in aryl halides: the effect of halide mass

“…The substituent effect is one of the most important concepts in chemistry, biochemistry, and related elds. [1][2][3][4] When substituted benzenes became the subject of a spectroscopic study, [5][6][7][8] there was much confusion regarding the results, such as the inuence of substituents on reactivity and stability of the very wide range of organic species containing aromatic moieties. [9][10][11][12] Analysis of mono-substituted benzenes reveals that the inuence of a single group will be essential.…”

Reactivity of hydrogen-bonded complexes of water, methanol, phenol and methyl amine

“…The hydrolysis of chlorosilanes 53,54 and carbon disulfide 55 with the participation of water hydrogen-bonded complexes proceeds much more easily than with the water monomer. Gibbs free energies for the interaction of carbonyl oxide with the water monomer is −49.7 kJ mol −1 , with the water dimer −29.5 kJ mol −1 , and the water trimer −22.0 kJ mol −1 .…”

Recent Advance in Low‐Dielectric‐Constant Organosilicon Polymers

“…Chlorosilanes can also undergo hydrolysis or alcoholysis to form siloxanes. [ 41‐42 ] Taking trimethylchlorosilane as an example (see Figure 2.5), trimethylchlorosilane can also be hydrolyzed in water to produce the silanol and hydrogen chloride. [ 41 ] Then silanols can undergo intermolecular condensation to produce siloxanes.…”

“…[ 41‐42 ] Taking trimethylchlorosilane as an example (see Figure 2.5), trimethylchlorosilane can also be hydrolyzed in water to produce the silanol and hydrogen chloride. [ 41 ] Then silanols can undergo intermolecular condensation to produce siloxanes. In alcohol, chlorosilanes can be alcoholysized to form siloxanes directly.…”