“…Existing state-of-the-art OPCPA systems operating at 3 µm can broadly be grouped into two classes: (i) high repetition rate sources (≥100 kHz) that operate at the multi-µJ-level, with the main reference systems at ICFO (131 µJ, 97 fs, 160 kHz), ELI Alps (152 µJ, 38 fs, 100 kHz), MBI Berlin (30 µJ, 70 fs, 100 kHz), and CELIA (8 µJ, 85 fs, 100 kHz) [11][12][13][14], and (ii) a very limited group with sources that can operate close or at the mJ-level but at lower (10-10,000 Hz) repetition rates, with the main reference systems at RIKEN (21 mJ, 70 fs, 10 Hz), Shanghai (13.3 mJ, 111 fs, 10 Hz), Singapore (2.7 mJ, 50 fs, 10 kHz), JILA (0.85 mJ, 420 fs, 1 kHz), and CAS Beijing (0.52 mJ, 100 fs, 1 kHz) [15][16][17][18][19]. State-of-the-art, high repetition rate mid-IR sources usually rely on periodically-poled lithium niobate (PPLN) for the non-linear medium [11,12,18] while mJ-level systems use mainly bulk material crystals, such as lithium niobate (LiNbO 3 , LN) [15,16] and potassium titanyl arsenate (KTiOAsO 4 , KTA) [20,21] (although in the latter case the output is already closer to 4 µm), clearly evidencing the potential of these crystals in withstanding and operating at high optical intensity levels.…”