Subzero‐Temperature Cathode for a Sodium‐Ion Battery

You, Ya; Yao, Hu‐Rong; Xin, Sen; Yin, Ya‐Xia; Zuo, Tong‐Tong; Yang, Chunpeng; Guo, Yu‐Guo; Cui, Yi; Li, Wan; Goodenough, John B

doi:10.1002/adma.201600846

Cited by 464 publications

(342 citation statements)

References 37 publications

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“…Our group reported a facile one‐step hydrothermal method to prepare PB/rGO composite utilizing the decomposition product of Fe 2+ to reduce graphene oxide (GO) (Figure j) . PB/CNT composite was synthesized by a one‐step hydrothermal method acting on Na 4 Fe(CN) 6 and CNTs in acid solution (Figure e–h) …”

Section: Synthesis Approachesmentioning

confidence: 99%

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Han

Cheng

et al. 2019

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Prussian blue analogues (PBAs, A2T[M(CN)6], A = Li, K, Na; T = Fe, Co, Ni, Mn, Cu, etc.; M = Fe, Mn, Co, etc.) are a large family of materials with an open framework structure. In recent years, they have been intensively investigated as active materials in the field of energy conversion and storage, such as for alkaline‐ion batteries (lithium‐ion, LIBs; sodium‐ion, NIB; and potassium‐ion, KIBs), and as electrochemical catalysts. Nevertheless, few review papers have focused on the intrinsic chemical and structural properties of Prussian blue (PB) and its analogues. In this Review, a comprehensive insight into the PBAs in terms of their structural and chemical properties, and the effects of these properties on their materials synthesis and corresponding performance is provided.

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Section: Synthesis Approachesmentioning

confidence: 99%

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Han

Cheng

et al. 2019

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“…

systems is hindered by the limited reserves and high cost of lithium. [4][5][6][7] In view of the recent studies in developing promising cathode materials, [8,9] one of the critical challenges in promoting the commercialization of SIBs is the lack of suitable anode materials with high capacities and rate capability as well as long-term cyclic performance. [4][5][6][7] In view of the recent studies in developing promising cathode materials, [8,9] one of the critical challenges in promoting the commercialization of SIBs is the lack of suitable anode materials with high capacities and rate capability as well as long-term cyclic performance.

…”

mentioning

confidence: 99%

Unveiling the Unique Phase Transformation Behavior and Sodiation Kinetics of 1D van der Waals Sb₂S₃ Anodes for Sodium Ion Batteries

Yao

Cui

et al. 2016

Advanced Energy Materials

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systems is hindered by the limited reserves and high cost of lithium. [1][2][3] Compared with LIBs, sodium ion batteries (SIBs) enjoy many advantages, such as low costs arising from abundance of sodium as well as potentially wider applications, including grid energy storage. [4][5][6][7] In view of the recent studies in developing promising cathode materials, [8,9] one of the critical challenges in promoting the commercialization of SIBs is the lack of suitable anode materials with high capacities and rate capability as well as long-term cyclic performance. The commercial graphite anode in LIBs cannot host the Na + ions whose diameter is 34% larger than the Li + ions in the commonly used carbonate-based electrolyte system, [10,11] although a recent study demonstrated the feasibility of cointercalation of Na + ions in ether-based electrolyte upon the formation of a ternary intercalation compound. [12] Many efforts have been devoted to investigating carbonaceous materials, such as hard carbon, [13] hollow carbon sphere, [14] carbon fiber, [15] as well as metals/metal chalcogenides, like Sn, [16] SnO x , [17] SnO 2 , [18] Bi 0.94 Sb 1.06 S 3, [19]and Sb, [20] as the potential anode materials. Compared with carbonaceous anodes possessing low storage capacities and unsafely low working potentials, anodes made from metal sulfides have been increasingly explored to achieve superior rate performance and high specific capacities. [21][22][23][24][25] For example, antimony trisulfide (Sb 2 S 3 ) has drawn significant attention because of its attractive reversible theoretical capacity of 946 mAh g −1 by accommodating 12 moles of Na + ions per Sb 2 S 3 mole and the improved cyclic performance owing to the Na 2 S phase serving as the buffer matrix to relieve the volume expansion. [26] So far, many methods have been adopted to successfully fabricate various Sb 2 S 3 -based anodes, such as reduced graphene oxide (rGO)/Sb 2 S 3 , [25] flower-like Sb 2 S 3 , [26] Sb 2 S 3graphite, [27] and rod-shaped Sb 2 S 3 , [28] which demonstrated exceptional reversible capacities and great potential for SIBs. However, the fundamental understanding of the underlying sodiation reaction mechanisms is still lacking and needs to be investigated in order to promote the wide application of the Sb 2 S 3 anodes.Carbon-coated van der Waals stacked Sb 2 S 3 nanorods (SSNR/C) are synthesized by facile hydrothermal growth as anodes for sodium ion batteries (SIBs). The sodiation kinetics and phase evolution behavior of the SSNR/C anode during the first and subsequent cycles are unraveled by coupling in situ transmission electron microscopy analysis with first-principles calculations. During the first sodiation process, Na + ions intercalate into the Sb 2 S 3 crystals with an ultrafast speed of 146 nm s −1 . The resulting amorphous Na x Sb 2 S 3 intermediate phases undergo sequential conversion and alloying reactions to form crystalline Na 2 S, Na 3 Sb, and minor metallic Sb. Upon desodiation, Na + ions extract from the nanocrystalline phases to leave behi...

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“…The metal-organicframeworks (MOFs) assembled by clusters/metal ions coordinated to organic ligands, usually form a uniform size, and possess interior cavities and porous shells after heat treating [6,7]. For example, Prussian blue (PB) containing the (C"N) À anions has been proved to have a high energy density, a small volume change during cycling, and stable rate capability in Na half-cells [8,9].…”

Section: Introductionmentioning

confidence: 99%

MgFe 2 O 4 hollow microboxes derived from metal-organic-frameworks as anode material for sodium-ion batteries

et al. 2017

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Subzero‐Temperature Cathode for a Sodium‐Ion Battery

Cited by 464 publications

References 37 publications

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Unveiling the Unique Phase Transformation Behavior and Sodiation Kinetics of 1D van der Waals Sb₂S₃ Anodes for Sodium Ion Batteries

MgFe 2 O 4 hollow microboxes derived from metal-organic-frameworks as anode material for sodium-ion batteries

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Subzero‐Temperature Cathode for a Sodium‐Ion Battery

Cited by 464 publications

References 37 publications

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Unveiling the Unique Phase Transformation Behavior and Sodiation Kinetics of 1D van der Waals Sb2S3 Anodes for Sodium Ion Batteries

MgFe 2 O 4 hollow microboxes derived from metal-organic-frameworks as anode material for sodium-ion batteries

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Unveiling the Unique Phase Transformation Behavior and Sodiation Kinetics of 1D van der Waals Sb₂S₃ Anodes for Sodium Ion Batteries