“…[3][4][5][6] In recent years, the demand for ultraviolet (UV, 𝜆 < 400 nm) coherent light sources, especially deep-ultraviolet (DUV, 𝜆 < 200 nm) lasers, in various frontier fields, is increasing sharply. [7][8][9][10] Therefore, after the unremitting efforts of generations of researchers, a large number of UV NLO crystals, such as 𝛽-BaB 2 O 4 , [11] LiB 3 O 5 , [12,13] KBe 2 BO 3 F 2 (KBBF), [14][15][16] and Sr 2 Be 2 B 2 O 7 , [17] DOI: 10.1002/adom.202300987 have been found. [18][19][20] However, up to now, only KBBF crystal really achieves the output of 177.3 nm laser by the direct frequency doubling process.…”