“…With increasing concern about the depletion of nonrenewable resources and environmental issues, lignocellulosic biomass has been recognized as a promising alternative to petroleum resources, which have been utilized to produce biofuels, chemicals, and biomaterials. − Cellulose nanofibrils (CNFs), mainly extracted from lignocellulosic biomass, have received a great deal of attention due to their excellent physical, mechanical, and chemical properties such as high elastic modulus (29–36 GPa) and tensile strength (2–6 GPa), large specific surface area (up to 600 m 2 /g), high aspect ratio (larger than 100), low density (1.32–1.58 g/cm 3 ), and reactive surfaces, along with biodegradability and renewability. − Due to their high aspect ratio and semicrystalline structure, CNFs exhibit remarkable tendency to form three-dimensionally entangled networks suitable for fabricating the cellulose nanopaper (CNP) by a self-assembly process such as vacuum filtration or casting. , CNP has been a hot topic which has attracted extensive interest from both academia and industries . Recent studies have shown that CNP is a promising material for use in many interdisciplinary fields such as electronic and photonic devices, , energy storage electrodes and separators, , electromagnetic interference (EMI) shielding materials, , sensors, , and so forth, in light of its good thermal stability, low thermal expansion coefficient (<10 ppm/K), tunable optical properties, and superior mechanical properties …”