“…Microbial electrolysis cell (MEC) is a lately designed biotechnological device that can reduce carbon dioxide for the generation of multi-carbon biofuels such as methane, acetate, etc. (called electromethangenesis) [8,9], or utilize organic matters in wastewater to form hydrogen (referred to as electrohydrogenesis) [10]. In an electrohydrogenesis MEC process, anode respiring bacteria (ARB, or exoelectrogens) populated at the anodic biofilms decompose organic substances into bicarbonate, protons and electrons [11]; the electrons by means of a small energy input, in addition to that (-0.3 V) produced by ARB, are transferred to the cathode and react with protons, generating H 2 via the hydrogen evolution reaction (HER): 2H + + 2e -→ H 2 (g) (-0.42 V at pH 7) [3,12].…”