2015
DOI: 10.1002/bkcs.10420
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Supramolecular Assembly of Tin(IV) Porphyrin Cations Stabilized by Ionic Hydrogen‐Bonding Interactions

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Cited by 11 publications
(11 citation statements)
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“…Although acidic media can convert POMo anions into neutral species, pyridinium and/or aqua groups in SnP can still interact with the terminal oxo groups (Mo_O) in POMo by hydrogen bondings. A previous report on self-assembly of SnP, in which SnP acts as a hydrogen bonding donor [12] supports the occurrence of hydrogen bondings in acidic media. Consequently, SnP-POMo nanoparticles seem to be stable even in acidic solutions.…”
Section: Contents Lists Available At Sciencedirectmentioning
confidence: 58%
See 1 more Smart Citation
“…Although acidic media can convert POMo anions into neutral species, pyridinium and/or aqua groups in SnP can still interact with the terminal oxo groups (Mo_O) in POMo by hydrogen bondings. A previous report on self-assembly of SnP, in which SnP acts as a hydrogen bonding donor [12] supports the occurrence of hydrogen bondings in acidic media. Consequently, SnP-POMo nanoparticles seem to be stable even in acidic solutions.…”
Section: Contents Lists Available At Sciencedirectmentioning
confidence: 58%
“…Tin(IV) porphyrin cation such as [Sn(TPy H P)(OH 2 ) 2 ] 6+ trans-diaquo [5,10,15,20-tetrakis(4-pyridinium) porphyrinato]tin(IV) was chosen as a porphyrin cation because it has a well-defined structure with multivalent charges [12] as well as interesting photocatalytic activities [13]. Fig.…”
mentioning
confidence: 99%
“…Trans-diaqua [5,10,15,20-tetrakis(4-pyridinium)porphyrinato]tin(IV) hexanitrate, [(TPyHP)Sn(OH 2 ) 2 ](NO 3 ) 6 , was prepared using a reported procedure [27]. TiO 2 nanoparticles (Degussa P25) were used as received.…”
Section: Methodsmentioning
confidence: 99%
“…Further, the Sn( iv ) porphyrins are ideal scaffolds for the construction of stable six-coordinated complexes with two trans -axial oxyanion ligands such as alkoxides and carboxylates. 33–39 Herein, we report the synthesis and characterization of two coordination frameworks, [Ag 2 (TPyP)Sn(OH) 2 ](NO 3 ) 2 ·(solv) x ( 1 ) and [Ag 2 (TPyP)Sn(INA) 2 ](OTf) 2 ·(CH 3 CN) 2 ( 2 ) (INA = isonicotinato anion, OTf = CF 3 SO 3 − ). The selection of silver cations over other metal ions is considered because of their versatile nature toward coordination geometries, mainly of the linear, trigonal, or tetrahedral types.…”
Section: Introductionmentioning
confidence: 99%