Abstract. Firn air provides plenty of old air from the near past, and can therefore be
useful for understanding human impact on the recent history of the
atmospheric composition. Most of the existing firn air records cover only
the last several decades (typically 40 to 55 years) and are insufficient to
understand the early part of anthropogenic impacts on the atmosphere. In
contrast, a few firn air records from inland sites, where temperatures and
snow accumulation rates are very low, go back in time about a century. In
this study, we report an unusually old firn air effective CO2 age of 93 years from Styx Glacier, near the Ross Sea coast in Antarctica. This is the
first report of such an old firn air age (>55 years) from a warm
coastal site. The lock-in zone thickness of 12.4 m is larger than at other
sites where snow accumulation rates and air temperature are similar.
High-resolution X-ray density measurements demonstrate a high variability of
the vertical snow density at Styx Glacier. The CH4 mole fraction and
total air content of the closed pores also indicate large variations in
centimeter-scale depth intervals, indicative of layering. We hypothesize that the
large density variations in the firn increase the thickness of the lock-in
zone and, consequently, increase the firn air ages because the age of firn
air increases more rapidly with depth in the lock-in zone than in the
diffusive zone. Our study demonstrates that all else being equal, sites
where weather conditions are favorable for the formation of large density
variations at the lock-in zone preserve older air within their open
porosity, making them ideal places for firn air sampling.