An in situ TiSi (Ti 5 Si 3 , TiSi)/TiC local reinforced steel matrix composite was successfully fabricated via combustion synthesis of Cu-Ti-Si system. XRD results show that the reinforced region of the composites is composed of Fe, Cu, TiSi and Ti 5 Si 3 as well as TiC phases. SEM observation shows that the morphologies of the Ti 5 Si 3 particles are coarse acicular/irregular particles and short fibrous/coarse elliptic shape in transition and reinforced region, respectively. TiC particles lie in transition region near the interface and their morphologies are polygon/quadrangle, with sizes ofϳ74 mm DTA analyses show that, without addition of Cu, slight TiSi (TiSi 2 and Ti 5 Si 3 ) compounds form via solid diffusion process. After addition of Cu, Cu and Ti reaction occurs firstly, forming a serious of Cu-Ti compounds, at the same time, the reaction heat ignites the subsequent reaction of CuTi and Si and according forms TiSi (Ti 5 Si 3 ) compounds.KEY WORDS: steel matrix composites; in situ reinforced locally; microstructures; combustion synthesis.
1401© 2009 ISIJ the TiSi MMCs can be fabricated at a relative low temperature.In the previous work of our group, a local in situ AlTiSi reinforced aluminium composite was successfully synthesized by SHS-cast process with reaction system of Al-Ti-Si.11) The purpose of this study is to develop a simplified route to produce a high quality TiSi particle reinforced steel MMCs.
Thermodynamic ConsiderationDuring the exothermic reactions in powder mixtures, Cu, Ti and Si may interact to form possible products due to the existence of the following chemical reactions. The Gibbs free energy, DG Q of reactions (1)- (7) has been calculated using the thermodynamic data from literature 12,13) and their results are shown in Fig. 2. Note that the overall 1 mol of the reactants was used for the calculation of changes in the Gibbs free energy, DG Q and the adiabatic temperature, T ad in order to compare the feasibility and tendency of these reactions. It can be seen that the DG Q of these reactions are all negative, which indicates that the seven reactions can take place. The DG Q of reactions (5)-(7) are less than those of reactions of (1)-(4), which indicates that reactions (5)-(7) are most likely to occur. Accordingly, it can be concluded that the displacement reaction (8) In order to confirm whether or not the combustion reactions can self-sustain, the critical value of copper content can be estimated by calculation of adiabatic temperature T ad . It is well known, in a combustion synthesis reaction process, the possible maximum temperature of an exothermic reaction can attain under adiabatic conditions. This maximum temperature is adiabatic temperature T ad , which can be calculated from the heat capacities and enthalpies of formation and transformation. 14) Usually, T ad can be used to ascertain whether or not a synthesis for a given material can be accomplished by a combustion synthesis method. It has been empirically suggested that combustion will not become self-sustaining unles...