Surface Imprinting of Cholesterol on Submicrometer Core−Shell Emulsion Particles

Pérez, Natalia; Whitcombe, Michael J.; Vulfson, Evgeny N.

doi:10.1021/ma001079v

Cited by 126 publications

(58 citation statements)

References 22 publications

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“…Core-shell particles are formed in a two-stage process from a seed latex; however, unlike the two-stage swelling (above) the seed particle (which may be cross-linked) is surrounded by a shell of new polymer in a second emulsion polymerization. This allows the imprinted sites to be positioned near 498,804 or at the surface [805][806][807] of the beads. In addition, superparamagnetic iron oxide particles can also serve as the core.…”

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confidence: 99%

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Andersson²,

et al. 2006

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Over 1450 references to original papers, reviews and monographs have herein been collected to document the development of molecular imprinting science and technology from the serendipitous discovery of Polyakov in 1931 to recent attempts to implement and understand the principles underlying the technique and its use in a range of application areas. In the presentation of the assembled references, a section presenting reviews and monographs covering the area is followed by papers dealing with fundamental aspects of molecular imprinting and the development of novel polymer formats. Thereafter, literature describing attempts to apply these polymeric materials to a range of application areas is presented.

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confidence: 99%

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Andersson²,

et al. 2006

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“…By choosing the appropriate support material, the particle size can be easily varied and specific properties such as fluorescence or magnetism of the core can be beneficial for separation or readout [32]. In this way, MIP nanoparticles for small molecules, e.g., cholesterol [33] but also for proteins, e.g., bovine hemoglobin [34] were prepared.…”

Section: Preparation Of Surface Imprinted Mipsmentioning

confidence: 99%

Enzymes as Tools in MIP-Sensors

et al. 2017

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Abstract:Molecularly imprinted polymers (MIPs) have the potential to complement antibodies in bioanalysis, are more stable under harsh conditions, and are potentially cheaper to produce. However, the affinity and especially the selectivity of MIPs are in general lower than those of their biological pendants. Enzymes are useful tools for the preparation of MIPs for both low and high-molecular weight targets: As a green alternative to the well-established methods of chemical polymerization, enzyme-initiated polymerization has been introduced and the removal of protein templates by proteases has been successfully applied. Furthermore, MIPs have been coupled with enzymes in order to enhance the analytical performance of biomimetic sensors: Enzymes have been used in MIP-sensors as "tracers" for the generation and amplification of the measuring signal. In addition, enzymatic pretreatment of an analyte can extend the analyte spectrum and eliminate interferences.

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“…In case of emulsion polymerization, small beads are created in an oil-water biphasic system stabilized by surfactant. As an example, cholesterol was imprinted using pyridinium 12-(cholesteryloxycarbonyloxy)dodecane sulfate [16].…”

Section: Organic Polymersmentioning

confidence: 99%

Molecularly Imprinted Electrochemical Sensors

Suryanarayanan

2010

Electroanalysis

220

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In this review, the applications of molecularly imprinted polymer (MIP) materials in the area of electrochemical sensors have been explored. The designs of the MIPs containing different polymers, their preparation and their immobilization on the transducer surface have been discussed. Further, the employment of various transducers containing the MIPs based on different electrochemical techniques for determining analytes has been assessed. In addition, the general protocols for getting the electrochemical signal based on the binding ability of analyte with the MIPs have been given. The review ends with describing scope and limitations of the above electrochemical based MIP sensors.

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Surface Imprinting of Cholesterol on Submicrometer Core−Shell Emulsion Particles

Cited by 126 publications

References 22 publications

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Enzymes as Tools in MIP-Sensors

Molecularly Imprinted Electrochemical Sensors

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