Surface modification of regenerated cellulose membrane based on thiolactone chemistry – A novel platform for mixed mode membrane adsorbers

Ye, Jianlong; Chu, Jiachen; Yin, Jian; Zhang, Yufeng; Meng, Jianqiang

doi:10.1016/j.apsusc.2020.145539

Cited by 9 publications

(9 citation statements)

References 35 publications

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“…5.5) were copolymerized by surface-initiated ATRP from a regenerated cellulose membrane. 94 Pre-functionalization of silica particles with the ATRP initiator were used to initiate the copolymerization of HEA and TLAam. 95 C.I.1.b.…”

Section: Reviewmentioning

confidence: 99%

“…A similar strategy was used to prepare a range of new HPLC stationary phases by immobilizing thiolactonecontaining thermoresponsive copolymers on aminopropylsilica in the presence of various acrylate compounds in THF or dioxane, 83 or for the preparation of mixed-mode membrane absorbers. 94 Other types of Michael acceptor Double modifications by aminolysis and subsequent thiol click reaction have also been performed with other type of Michael acceptor, such as methacrylates 94 or maleimides. 80 However, it is worth mentioning that primary amines can react with maleimides.…”

Section: Polymer Chemistry Reviewmentioning

confidence: 99%

“…Recently, methyl methacrylate and a thiolactonecontaining styrene monomer (Figure 5.5) were copolymerized by surface-initiated ATRP from a regenerated cellulose membrane. 94 Pre-functionalization of silica particles with the ATRP initiator were used to initiate the copolymerization of HEA and TLAam. of Durmaz and copolymerized with butyl-functionalized oxanorbornene monomer by ring-opening metathesis polymerization using the first generation Grubbs catalyst at room temperature.…”

Section: Controlled Radical Polymerizationmentioning

confidence: 99%

“…A similar strategy was used to prepare a range of new HPLC stationary phases by immobilizing thiolactone-containing thermoresponsive copolymers on aminopropyl-silica in the presence of various acrylate compounds in THF or dioxane, 83 or for the preparation of mixed-mode membrane absorbers. 94…”

Section: Introduction Of Thiolactone Functional Group On Macromoleculesmentioning

confidence: 99%

“…Double modifications by aminolysis and subsequent thiol click reaction have also been performed with other type of Michael acceptor, such as methacrylates 94 or maleimides. 80 However, it is worth mentioning that primary amines can react with maleimides.…”

Section: Introduction Of Thiolactone Functional Group On Macromoleculesmentioning

confidence: 99%

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Thiolactone chemistry, a versatile platform for macromolecular engineering

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Mongkhoun

2022

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Section: Reviewmentioning

confidence: 99%

Section: Polymer Chemistry Reviewmentioning

confidence: 99%

Section: Controlled Radical Polymerizationmentioning

confidence: 99%

Section: Introduction Of Thiolactone Functional Group On Macromoleculesmentioning

confidence: 99%

Section: Introduction Of Thiolactone Functional Group On Macromoleculesmentioning

confidence: 99%

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Thiolactone chemistry, a versatile platform for macromolecular engineering

Illy

Mongkhoun

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Green nanoarchitectonics for next generation electronics devices: patterning of conductive nanowires on regenerated cellulose substrates

et al. 2022

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Polymer-modified regenerated cellulose membranes: following the atom transfer radical polymerization concepts consistent with the principles of green chemistry

Zaborniak

Chmielarz

2022

Cellulose

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Synthetic routes for functionalization of cellulose membranes by polymer chains characterized by controlled structures are constantly developed to precisely adjust the properties of the prepared material while minimizing the impact on the membrane performance. The review presents a critical and integrative evaluation of prior research on atom transfer radical polymerization (ATRP) techniques, emphasizing methods carried out with diminished catalyst concentration that were used for grafting polymers from cellulose membranes. The paper introduces cellulose as a naturally-derived and efficient material for filtration membrane production focusing on the fundamentals of the cellulose structure, and the reasons, and advantages of using cellulose as a membrane-built substrate. It also covers fundamental mechanistic aspects of ATRP and introduces the basic principles of low ppm ATRP methods focusing on the latest reports. The works up to date concerning the functionalization of cellulose membranes by the “classic” ATRP concept, paying attention to the concentration of the complex used and synthetic methodology, as well as the final properties of the obtained materials are shown. Subsequent, low ppm ATRP techniques are discussed against the background of the “classic” approach in synthesizing bioactive surfaces and functional biomaterials based on the structure of cellulose membranes, with emphasis on the advantages of methods with diminished catalyst level as a more cost-effective and thus more compatible to use in a commercial application. The present work is a concise and perspective review, which shows both the achievements to date and broad prospects for the development of this issue in the coming years. Graphical Abstract

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Surface modification of regenerated cellulose membrane based on thiolactone chemistry – A novel platform for mixed mode membrane adsorbers

Cited by 9 publications

References 35 publications

Thiolactone chemistry, a versatile platform for macromolecular engineering

Thiolactone chemistry, a versatile platform for macromolecular engineering

Green nanoarchitectonics for next generation electronics devices: patterning of conductive nanowires on regenerated cellulose substrates

Polymer-modified regenerated cellulose membranes: following the atom transfer radical polymerization concepts consistent with the principles of green chemistry

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