To solve the problems of brittleness, high cost, and the complicated construction process of traditional filling materials for filling abandoned roadways, various aspects of the physical and mechanical properties of the materials were studied using laboratory tests and were applied in coal mines. The research shows that the self-developed inorganic cementitious filling material has the advantages of being low cost, easy to cut and wash, and having good filling performance. A foaming agent is a direct factor in controlling the volume expansion of inorganic cementitious filling materials; the increase in the volume of slurry foaming with the addition of a foaming agent initially showed a large and then a small trend with a foaming agent dosage of 100 g. The increase in the volume of slurry foaming is the largest at 56.28%. The effect of the B material (calcium stearate+ J85 rapid-setting agent) on the foaming time and the number of foaming times of the slurry was significant. Foam stabilizers in the B material make the slurry particles uniformly distributed inside the slurry, while quick-setting agents control the initial and final setting time by affecting the slurry setting speed. The water/cement ratio directly affects the foaming times of the slurry but has little effect on the foaming time and setting speed. When the water/cement ratio is less than 1:2, the slurry foaming effect is poor, and the foaming volume remains unchanged. The strength of the material is significantly affected by the proportion of B material and the amount of blowing agent, and the compressive strength of materials with different compositions and ratios varies greatly. A whole set of systems of new inorganic gelatinized abandoned roadway filling materials was researched and applied in coal mines, achieving good results.