Suspension and emulsion aqueous cationic homopolymerization and copolymerization of cyclohexyl vinyl ether by B(C6F5)3 initiating system

You, Shichao; Wei, Xuling; Liu, Ruofan; Zhao, Chenqi; Zhao, Ming; Shi, Qisong; Gong, Guangbi; Wu, Yibo

doi:10.1016/j.polymer.2022.125183

Cited by 5 publications

(1 citation statement)

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“…This including polymerization under mild reaction conditions, reduction of the use of organic solvents, application of non-toxic catalysts, etc. In previous studies, several research group introduced a polymerization system utilizing ionic liquids [8][9][10][11][12][13] or water [14][15][16][17][18][19][20][21][22][23] as the reaction media in cationic polymerization, thereby reducing the reliance on organic solvents. Notably, this polymerization process can be conducted at room temperature, overcoming the significant energy consumption challenges posed by traditional cationic polymerization processes.…”

Section: Introductionmentioning

confidence: 99%

Recent advances on visible light induced cationic polymerization

Feng

Liu

et al. 2023

Journal of Polymer Science

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Cationic polymerization is an important branch of polymer chemistry. Traditional cationic polymerization must be carried out in anhydrous and low temperature environment, with harsh operating conditions, high operating costs and high energy consumption. Visible light induced cationic polymerization is simple, environmentally friendly, and low‐cost, so it has become a research hotspot of living cationic polymerization. This paper gives an overview of the recent advances (mainly from 2015 to 2023) on visible‐light‐induced cationic polymerization, with a focus on visible‐light‐initiated and visible‐light‐controlled cationic polymerization. On the basis of controlling cationic polymerization to achieve macromolecular reaction engineering, the realization of temporal scale control will be the main development direction in the future.

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Section: Introductionmentioning

confidence: 99%

Recent advances on visible light induced cationic polymerization

Feng

Liu

et al. 2023

Journal of Polymer Science

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Stereoselective Construction of Tertiary Homoallyl Alcohols and Ethers by Nucleophilic Substitution at Quaternary Carbon Stereocenters

2022

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An efficient method for the stereoselective construction of tertiary CÀ O bonds via a stereoinvertive nucleophilic substitution at the quaternary carbon stereocenter of cyclopropyl carbinol derivatives using water, alcohols and phenols as nucleophiles has been developed. This substitution reaction proceeds under mild conditions and tolerates several functional groups, providing a new access to the stereoselective formation of highly congested tertiary homoallyl alcohols and ethers.

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