“…4 Self-assembly plays a vital role in nanotechnology and directs the fabrication of structurally diverse architectures with welldefined morphologies and sizes, such as nanotubes, nanosheets, nanowires, polygons, nanodiscs, polyhedra, nanocubes, vesicles, nanospheres, and branched nanocrystals, [5][6][7][8] which show potential in a wide range of applications including photovoltaics, 9 energy storage and conversion, 10,11 memory devices, tissue regeneration, sensors, drug delivery, ion-channel regulation, biomedical applications, and nanoreactors. [11][12][13][14][15][16][17][18] The various forces that control the molecular assembly or organization are hydrogen bonding interactions, van der Waals attractions, steric repulsions, capillary forces during solvent evaporation, electrostatic interactions, π-π stacking, and chargetransfer interaction. 12,14 Moreover, shape-shifting and sizegrowth of nanostructures can also be stimulated by external factors including light, temperature, nature of solvent, variation in concentration, pH, and ionic strength owing to the reversible and dynamic nature of these non-covalent interactions.…”