Suzuki cross-coupling of aryl bromides catalyzed by cyrhetrenylphosphine complexes of palladium (II)

A variety of 2,3-diiodinated biphenyl and iodinated meta-terphenyl derivatives were synthesized by a regioselective Suzuki-Miyaura cross-coupling reaction of 5-substituted 1,2,3triiodobenzenes. By using 1 equiv. of arylboronic acid, the Suzuki-Miyaura reaction yielded 2,3-diiodinated biphenyl derivatives with excellent regioselectivity. The coupling reaction predominantly occurred at the terminal position of the P. O.

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Synthesis of Diiodinated Biphenyls and Iodinated meta‐Terphenyls by Regioselective Suzuki–Miyaura Cross‐Coupling Reactions of 5‐Substituted 1,2,3‐Triiodobenzenes

Al‐Zoubi

Al-Jammal

El‐khateeb

et al. 2015

Eur J Org Chem

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Dicyclohexylphosphino cyrhetrene: Synthesis, characterization and catalytic evaluation toward Suzuki-Miyaura cross-coupling reaction of aryl bromides and chlorides

Sierra

Brito

Fuentealba

et al. 2018

Inorganic Chemistry Communications

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Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions

Sierra

Bhuvanesh

Reibenspies

et al. 2014

Journal of Organometallic Chemistry

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Suzuki cross-coupling of aryl bromides catalyzed by cyrhetrenylphosphine complexes of palladium (II)

Cited by 3 publications

References 17 publications

Synthesis of Diiodinated Biphenyls and Iodinated meta‐Terphenyls by Regioselective Suzuki–Miyaura Cross‐Coupling Reactions of 5‐Substituted 1,2,3‐Triiodobenzenes

Synthesis of Diiodinated Biphenyls and Iodinated meta‐Terphenyls by Regioselective Suzuki–Miyaura Cross‐Coupling Reactions of 5‐Substituted 1,2,3‐Triiodobenzenes

Dicyclohexylphosphino cyrhetrene: Synthesis, characterization and catalytic evaluation toward Suzuki-Miyaura cross-coupling reaction of aryl bromides and chlorides

Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions

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