In this work, we investigate the propagation of magneto-inductive waves (MIWs) in ordering magnetic metamaterial (MM) structures. The proposed non-homogeneous MM slab consists of 9 × 9 MM unit cells constructed from a five-turn spiral embedded on an FR-4 substrate. External capacitors with the value of 40 pF or 50 pF were added to control the resonant frequency of each unit cell in accordance with the waveguide configurations. The characteristics of metamaterial structures, such as negative permeability, current ratio, transmission response, and field distribution in the waveguide, have been thoroughly analyzed by simulation and experiment. Because of the strong magnetic field confinement in the waveguide, the transmittance after nine elements of the non-homogeneous MM slab is 5.2 times greater than that of the homogeneous MM slab. This structure can be applied to the planar near-field wireless power transfer, position sensor, and low-frequency communication.