“…Some of these issues are not well understood although the hysteretic behavior of such materials, especially thin films of Transition Metal Oxides (TMO) like Ta 2 O 5 , Nb 2 O 5 , TiO 2 , NiO, Cu 2 O, and Group III and IV oxides (Al 2 O 3 , SiO x ), in metal-insulator-metal (MIM) vertical devices have been studied for decades [1][2][3][4][5][6][7][8]. The diverse semiconductor [9][10][11], polymer [12,13], and correlated oxide systems [10,[14][15][16][17] exhibited switching under electric pulsing. In recent years, interest in various oxide-based systems switchable by an electric pulse has grown quite dramatically leading to important breakthroughs and exposing various fundamental problems related to mechanisms of bipolar (driven by alternating positive and negative biasing to close the I-V hysteresis loop) and unipolar (driven by the bias of one polarity) switching behavior [18][19][20].…”