Synergistic combination of metal oxide adsorbents for enhanced fouling control and metal removal in a submerged membrane adsorber

Weerasekara, N.A.; Choo, Kwang‐Ho

doi:10.1016/j.memsci.2015.04.057

Cited by 9 publications

(1 citation statement)

References 40 publications

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“…[25][26][27] In recent decades, pressure-driven membrane separation technology has been widely used in desalination, 28,29 removal of pollutants in water, 30 and separation or removal of metal ions. [31][32][33][34] For example, to separate cesium and rubidium from other alkaline metal ions in aqueous solutions, Jia et al 35 developed a novel adsorption membrane by in-situ preparation of Prussian blue (PB) nano-layer on porous polyacrylonitrile (PAN) membranes, results indicated that the Cs + maximum adsorption capacity attained 0.714 mmol g À1 , and the selectivity factors of Cs + versus Li + , K + , and Na + were 41.76, 35.50, and 23.67, respectively. Ding et al 36 fabricated AMP-PAN membranes to eliminate radioactive cesium from water through the filtration adsorption process.…”

Section: Introductionmentioning

confidence: 99%

Fabrication and performance of the ammonium molybdophosphate/polysulfone mixed matrix membranes for rubidium adsorption in aqueous solution

Sun

Wang

Zhang

et al. 2021

J of Applied Polymer Sci

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The separation of the rare and precious metal rubidium is still a challenge to hydrometallurgy and material science. A novel ammonium molybdophosphate (AMP)/polysulfone (PSf) mixed matrix membrane for rubidium adsorption and separation was prepared successfully by NIPs method via immobilizing AMP into the PSf porous membrane. FTIR, XRD, SEM tests indicate that AMP is embedded into the PSf matrix, and its crystalline structure remains intact. WCA tests show that the membrane surfaces are more and more hydrophilicity with the AMP blending content increasing. The fluxes increase approximately linearly from 210.2 to 370.2 L m À2 h À1 with the AMP content while the bovine serum albu rejections decrease from 97.8% to 88.5%. The Rb + adsorption capacities of the membranes studied as a function of contact time, pH, Rb + concentration, temperature, presence of various interference ions, and the Rb + capacity is up to 98.4 mg g À1 at the optimal adsorption conditions. The Rb + adsorption on the AMP/PSf porous membrane complies with Langmuir adsorption isotherms and pseudo-second-order kinetic model. Finally, the reusability in Rb + adsorption of the AMP/PSf porous membrane is investigated, and the recovery rate can still be maintained above 95% after five adsorption-desorption recycles.

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