“…These were prepared, in almost quantitative yields (91-98%) as previously reported for 1g, 8 by reacting the appropriate phenols with 4-bromo-2-methylbut-2ene in acetone in the presence of K 2 CO 3 and KI.…”
2,2-Dimethylchromans 3a-g are synthesized in good yields by a one-pot reaction of the aryl prenyl ethers 1a-g with a catalytic amount of Mo(CO) 6 in refluxing toluene.
SchemeDownloaded by: UC Santa Barbara. Copyrighted material.
“…These were prepared, in almost quantitative yields (91-98%) as previously reported for 1g, 8 by reacting the appropriate phenols with 4-bromo-2-methylbut-2ene in acetone in the presence of K 2 CO 3 and KI.…”
2,2-Dimethylchromans 3a-g are synthesized in good yields by a one-pot reaction of the aryl prenyl ethers 1a-g with a catalytic amount of Mo(CO) 6 in refluxing toluene.
SchemeDownloaded by: UC Santa Barbara. Copyrighted material.
Das Neohesperidosid (I) wird mit den Aldehyden (IIa) bzw. (IIb) zu den Chalkonglykosiden (III) kondensiert, die ohne Isolierung ausschließlich zu den Flavanonglykosiden (IVa) bzw. (IVb) cyclisiert werden.
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