Synthese und reaktionen von äthyliden-methylsuccinimid

Schoch, Siegrid; Klein, Gerhard; Linsenmeier, U.; Rüdiger, W.

doi:10.1016/s0040-4039(01)92288-9

Cited by 7 publications

(4 citation statements)

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“…The same conclusion was drawn from high resolution proton NMR spectroscopy of the phytochromobilin undecapeptide (LAGARIAS and RAPOPORT 1980). This investigation was based on a previous extensive investigation of a phycocyanobilinpeptide, a synthetic reference peptide lacking the chromo- SCHOCH et al 1974) phore and free phycocyanobilin (LAGARIAS et al 1979). Double resonance experiments with the chromopeptide confirmed the hydrogenated ring A and the substitution at C-3 1 .…”

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confidence: 55%

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Chromophores in Photomorphogenesis

Rüdiger¹,

Scheer²

1983

Photomorphogenesis

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Library of Congress Cataloging in PublicationThis work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically those of translation, reprinting, re-use of illustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks.Under §54 of the German Copyright Law where copies are made for other than private use, a fee is payable to "Verwertungsgesellschaft Wort" Munich. © by Springer-Verlag Berlin-Heidelberg 1983 Printed in GermanyThe use of registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use.Typesetting, printing and bookbinding: Universitätsdruckerei H. Stürtz AG, Würzburg.

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confidence: 55%

“…4). The C-3 thioether (12) yields the maleimide (13) whereas the C-3 1 -thioether yields the ethylidene succinimide (la) (SCHOCH et al 1974). Because (la) was the only product obtained from phytochrome in this reaction ; see also Sect.…”

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confidence: 99%

Chromophores in Photomorphogenesis

Rüdiger¹,

Scheer²

1983

Photomorphogenesis

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“…Die häufigsten Phycobiline sind Phycocyanobilin (Struktur I) und Phycoerythrobilin (Struktur II (SCHOCH et al 1976). Der früher angewendete Abbau mit Chrom säure in der Hitze liefert die Ethylidenverbindung dagegen nur in geringerer Ausbeute.…”

Section: Struktur Und Proteinbindung Der Phycobilineunclassified

“…Der früher angewendete Abbau mit Chrom säure in der Hitze liefert die Ethylidenverbindung dagegen nur in geringerer Ausbeute. Somit wurde durch das Studium der Chemie von Succinimiden ein neues Abbauverfahren ("Chromsäure-Ammoniak-Abbau") entwickelt, das in zwischen mit Erfolg auf Biliproteide angewendet worden ist (SCHOCH et al 1976, KLEIN und RÜDIGER 1978 (KOST und RÜDIGER 1974), reagieren beim Chromsäure-Ammoniak-Abbau einheitlich und in guter Ausbeute zum E-konfigurierten Ethylidenprodukt. Damit ist die relative Konfiguration der drei chiralen Zentren im Thioether (d. h. im proteingebundenen Chromophor) festgelegt.…”

Section: Struktur Und Proteinbindung Der Phycobilineunclassified