Synthese ungesättigter 1‐Acyl‐3‐methyl‐pyrazole

Nach der Mangan(IV)‐Methode wurden Methylmethacrylat auf Kartoffelsärke und Dextran sowie 1‐Acryloyl‐3‐methyl‐pyrazol und 1‐Methacryloyl‐3,5‐dimethyl‐pyrazol auf Kartoffelstärke gepfropft. Für die Pfropcopolymerisation von Kartoffelstärke mit Methylmethacrylat wurde der Einfluß der Säurekonzentration, der Lösungsmittelzu sammensetzung, der Anwesenheit von Permanganat und der Gelatinierung der Stärke untersucht.

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Mangan(IV)‐initiierte Pfropfcopolymerisation von Methymethacrylat und anderen Acrylmonomeren auf Stärke und Dextran

Carlsohn

Hartmann

1982

Acta Polymerica

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ChemInform Abstract: SYNTHESIS OF UNSATURATED 1‐ACYL‐3‐METHYLPYRAZOLES

Carlsohn¹,

Hipler²,

Breuer³

et al. 1981

Chemischer Informationsdienst

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Biocide polymere, 12. Synthese und hydrolyseverhalten von copolymeren aus methacryl‐ und acrylsäure sowie 1‐methacryloyl‐ und 1‐acryloyl‐3‐methylpyrazol

et al. 1985

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The radical copolymerization of 1-acryloyl-and 1-methacryloyl-3-methylpyrazole (1 a and l b ) with acrylic acid or methacrylic acid in solution was studied. Copolymers containing carboxyl as well as 3-methyl-1-pyrazolylcarbonyl groups as side chains were prepared via the reaction of 3(5)-methylpyrazole with activated poly(acry1ic acid)s of various molecular weights.The hydrolysis data suggest that the release rates of the biocide 3(5)-methylpyrazole from the investigated copolymers vary significantly depending on the content of carboxyl groups and their change during the hydrolysis.

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Synthese ungesättigter 1‐Acyl‐3‐methyl‐pyrazole

Cited by 4 publications

References 3 publications

Mangan(IV)‐initiierte Pfropfcopolymerisation von Methymethacrylat und anderen Acrylmonomeren auf Stärke und Dextran

Mangan(IV)‐initiierte Pfropfcopolymerisation von Methymethacrylat und anderen Acrylmonomeren auf Stärke und Dextran

ChemInform Abstract: SYNTHESIS OF UNSATURATED 1‐ACYL‐3‐METHYLPYRAZOLES

Biocide polymere, 12. Synthese und hydrolyseverhalten von copolymeren aus methacryl‐ und acrylsäure sowie 1‐methacryloyl‐ und 1‐acryloyl‐3‐methylpyrazol

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