Syntheses and coordination chemistry of thiosemicarbazone-based titanium complexes

Abstract

Two routes leading to thiosemicarbazone-based complexes are reported with the view of developing ionic titanium complexes as cytotoxic metallodrugs. The reaction of bis(π-η5:σ-η1-pentafulvene)titanium complexes with most thiosemicarbazones gives κ2N,S thiosemicarbazonido...