Syntheses, structures and magnetic property of two copper complexes with cyclic dimer and 2D herringbone-like network built from helical motif

Crystal structure of (bis(2,2′-bipyridine-κ 2 N,N′))-(3,5-dinitrosalicylato-κ 2 O,O′)nickel(II), C27H18N6NiO7

“…Though the functional groups such as NO 2 are able to form robust and strong hydrogen bond, the syntheses of metalorganic supramolecular assemblies employing organic ligands with NO 2 groups are limited [5]. Up to now, only 3,5-dinitrosalicylato complexes have been reported [6,7]. In the title crystal structure the Ni(II) atom exhibits an octahedral coordination geometry, defined by four N atoms of two 2,2′-bipy ligands and two O atoms from one 3,5-(NO 2 ) 2 sal ligand.…”

Crystal structure of catena-triaqua(5-methoxyisophthalate)- cadmium(II)—water (1:2), [Cd(C9H6O5)(H2O)3] · 2H2O

“…The motivation comes notonly from their application as functional materials but is also due to the intriguing structural architectures [1][2][3][4].Inprinciple, the mosteffective approach for the construction of MOFs is to rationally modify the building blocks and to control the assembled motifs for required products via selecting different organic ligands [5,6]. 5-methoxyisophthalate (CH 3 O-H 2 ip) may serve as as uitable building block to construct novel coordination polymers due to the existence of anoncoordinating CH 3 Ogroup on the aromatic backbone, which will have aprofound impact on the electron density of such aligand and therefore different physical and chemical properties [7][8][9].…”

CRYSTAL STRUCTURE OF CATENA- DIAQUA( N - p - ACETAMIDOBENZENE- SULFONYLGLYCINATO)HOLMIUM(III)4,4'-BIPYRIDINEHEPTAHYDRATE, [HO(C10H11N2O)5S)3(H2O)2]·C10H8N2·7H2O

“…In the past few years, the design and synthesis of metal organic materials have attracted increasing attention due to their potential applications in the field of optics, electronics, catalysis and magnetism [1][2][3][4][5][6]. Metal ions can be found as isolated clusters or chains which are connected to each other by the linkers.…”