Syntheses, structures and properties of chiral Ln(III) coordination polymers based on ( R )-4-(4-(1-carboxyethoxy)phenoxy)-3-fluorobenzoic acid

Gao, Chang-Hui; Zhang, Lin; Hou, Guang-Feng; Ma, Dongsheng; Jiang, Wen; Yu, Ying‐Hui

doi:10.1016/j.inoche.2017.03.001

Inorganic Chemistry Communications

2017

DOI: 10.1016/j.inoche.2017.03.001

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Syntheses, structures and properties of chiral Ln(III) coordination polymers based on ( R )-4-(4-(1-carboxyethoxy)phenoxy)-3-fluorobenzoic acid

Chang-Hui Gao

Lin Zhang

Guang-Feng Hou

et al.

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Cited by 9 publications

References 27 publications

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Solvothermal Syntheses, Crystal Structures and Catalytic Properties of Four Chiral Compounds Built from (R)‐4‐(4‐(1‐Carboxyethoxy)penoxy) Benzoic Acids

Zhang

Hou

et al. 2017

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A series of chiral metal−organic compounds [Ag(cpfa)(phen)] (1), [Ag(cpna)(phen)] (2), [Cu(cpna)(phen)]•2H2O (3), [Cd2(cpna)2(phen)2]n (4) (H2cpfa=(R)‐4‐(4‐(1‐carboxyethoxyphenoxy)phenoxy‐3‐fluorobenzoic acid; H2cpna=(R)‐4‐(4‐(1‐carboxyethoxy)phenoxy)‐3‐nitrobenzoic acid; phen=1,10‐phenanthroline) has been successfully obtained via solvothermal reactions and characterized by IR spectra, elemental analyses, thermo gravimetric analyzer (TGA), solid‐state circular dichroism (CD) and powder X‐ray diffraction (PXRD). Compounds 1–4 all crystallize in chiral space groups and their CD spectra exhibit obvious positive or negative Cotton effects, indicating their homochirality. Rich hydrogen bonds based on carboxylic groups and π‐π interactions between adjacent phen molecules are present in the four compounds. It is also found that the pH value and reactant ratio have an impact on the growth of the compounds. In addition, their asymmetric catalytic activities for Henry reaction have also been investigated.

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Solvothermal Syntheses, Crystal Structures and Catalytic Properties of Four Chiral Compounds Built from (R)‐4‐(4‐(1‐Carboxyethoxy)penoxy) Benzoic Acids

Zhang

Hou

et al. 2017

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Synthetic strategies towards chiral coordination polymers

Tay

Kyratzis

Thoonen

et al. 2021

Coordination Chemistry Reviews

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Highly luminescent lanthanide complexes constructed by Bis-tridentate ligand and as sensor for Et2O

Zheng

Ding

Zeng

2018

Inorganic Chemistry Communications

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Syntheses, structures and properties of chiral Ln(III) coordination polymers based on ( R )-4-(4-(1-carboxyethoxy)phenoxy)-3-fluorobenzoic acid

Cited by 9 publications

References 27 publications

Solvothermal Syntheses, Crystal Structures and Catalytic Properties of Four Chiral Compounds Built from (R)‐4‐(4‐(1‐Carboxyethoxy)penoxy) Benzoic Acids

Solvothermal Syntheses, Crystal Structures and Catalytic Properties of Four Chiral Compounds Built from (R)‐4‐(4‐(1‐Carboxyethoxy)penoxy) Benzoic Acids

Synthetic strategies towards chiral coordination polymers

Highly luminescent lanthanide complexes constructed by Bis-tridentate ligand and as sensor for Et2O

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