Synthesis and catalytic performance of bimetallic NiMo- and NiW-ZSM-5/MCM-41 composites for production of liquid biofuels

Subsadsana, Maliwan; Kham-or, Pitsanuphong; Sangdara, Pakpoom; Suwannasom, Pirom; Ruangviriyachai, Chalerm

doi:10.1016/s1872-5813(17)30039-7

Cited by 17 publications

(11 citation statements)

References 26 publications

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“…The selectivity of Ni metal in the hydrodeoxygenation of octanoic acid was found to improve with the addition of Mo according to previous research [19]. It was formerly reported that the hydrocracking of crude palm oil in the presence of NiMo-ZSM-5/MCM-41 exhibited good performance with over 63.40 wt% conversion, which is higher in comparison to the conversion by Ni-ZSM-5/MCM-41 (53.34 wt%) [20]. Moreover, Mo which presents as metal oxide provides surface oxygen vacancy which contributes to capturing oxygencontaining compounds, such as: FFA [3,11,15].…”

Section: Introductionmentioning

confidence: 59%

Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica

Trisunaryanti

Larasati

Triyono

et al. 2020

Bull. Chem. React. Eng. Catal.

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In order to overcome the depletion of energy resources, the production of fuel from a renewable source (green fuel) has aroused attention. The present work serves as a comparative study for green fuel production by utilizing monometallic Ni and bimetallic NiMo loaded on amine-functionalized mesoporous silica (MS). Two types of catalysts, denoted as Ni/NH2-MS and NiMo/NH2-MS, were prepared and evaluated for its catalytic activity in the hydrotreatment of waste coconut oil (WCO) at 450 ℃ under the flow of H2 gas (20 mL.min-1). Each catalysts were characterized by using X-ray Diffraction (XRD), Atomic Absorption Spectrometer (AAS), Transmission Electron Microscopy (TEM), Scanning Electron Microscopy (SEM), and Fourier Transform Infra Red (FTIR). Study of selectivity by GC-MS showed that gasoline-range hydrocarbon, especially n-undecane, was the major compound in the liquid products generated by the two amine-functionalized catalysts prepared in this study. The result showed that monometallic Ni/NH2-MS with surface area, total pore volume, nickel loading and average pore diameter 328.68 m2.g-1, 0.25 cm3.g-1, 1.90 wt%, 3.10 nm, respectively, exhibited the best performance in producing liquid hydrocarbon and generated higher level of liquid product (77.9 wt%) than bimetallic NiMo/NH2-MS (76.3 wt%). However, it is highlighted that adding 1.08 wt% of Mo in bimetallic NiMo/NH2-MS comprising 0.83 wt% of Ni improved the catalyst selectivity towards producing higher level of gasoline-range hydrocarbon (43 wt%). The bimetallic NiMo/NH2-MS prepared was found to have surface area, total pore volume, and average pore diameter of 325.13 m2.g-1, 0.14 cm3.g-1, 3.22 nm, respectively. Copyright © 2020 BCREC Group. All rights reserved

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Section: Introductionmentioning

confidence: 59%

Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica

Trisunaryanti

Larasati

Triyono

et al. 2020

Bull. Chem. React. Eng. Catal.

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“…Another area of extensive concern in synthesizing mesoporous silicas is to employ low-cost silica-containing sources. Up to now, researchers have successfully synthesized MCM-41 using a diversity of silica-containing precursors, such as (i) natural minerals (natural clay [ 21 ], diatomite [ 22 ], kaolin [ 23 ], and so on), and (ii) anthropogenic solid wastes (rice husk ash [ 24 ], peanut shell ash [ 25 ], wheat straw ash [ 26 ], coal slag [ 27 ], coal fly ash [ 28 ], and so on). Coal fly ash (CFA) is a byproduct of coal-fired power plants, originating from the nonflammable ashes in coal, and it is collected by precipitators from flue gas.…”

Section: Introductionmentioning

confidence: 99%

Efficient Activation of Coal Fly Ash for Silica and Alumina Leaches and the Dependence of Pb(II) Removal Capacity on the Crystallization Conditions of Al-MCM-41

Zhang

2021

IJMS

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In this study, four different coal fly ashes (CFAs) were used as raw materials of silica and alumina for the preparation of the alumina-containing Mobil Composition of Matter No. 41 (Al-MCM-41) and the exploration of an activation strategy that is efficient and universal for various CFAs. Alkaline hydrothermal and alkaline fusion activations proceeded at different temperatures to determine the best treatment parameters. We controlled the pore structure and surface hydroxyl density of the CFA-derived Al-MCM-41 by changing the crystallization temperature and aging time. The products were characterized by small-angle X-ray diffraction, nitrogen isotherms, Fourier-transform infrared spectroscopy, 29Si silica magic-angle spinning nuclear magnetic resonance, and transmission electron microscopy, and they were then grafted with thiol groups to remove Pb(II) from aqueous solutions. This paper innovatively evaluates the CFA activation strategies using energy consumption analysis and determines the optimal activation methodology and parameters. This paper also unveils the effect of the crystallization condition of Al-MCM-41 on its subsequent Pb(II) removal capacity. The results show that the appropriate selection of crystallization parameters can considerably increase the removal capacity over Pb(II), providing a new path to tackle the ever-increasing concern of aquic heavy-metal pollution.

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“…Minyak nabati lain yang digunakan adalah CPO dan minyak kedelai. Peneliti yang memanfaatkan CPO sebagai bahan baku antara lain [8][9][10] [11] dan peneliti yang memanfaatkan minyak kedelai sebagai bahan baku adalah [12]. [9] membuat biofuel dari CPO dengan katalis Na2CO3 sebesar 15% dan suhu reaktor 450 o C didapatkan yield produk 90,84%.…”

Section: Perbandingan Bahan Baku Yang Berbeda Terhadap Yield Productunclassified

Proses Pembuatan Biofuel dengan Metode perengakahan Menggunakan Katalis Padat

Budianto

Sari

Monica

et al. 2021

JOICHE

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<table class="NormalTable"><tbody><tr><td width="200"><span class="fontstyle0">The development of population growth causes of fuels need increasing. Because of<br />that reason, it necessary to create alternative fuels which are friendly to the<br />environment to meet the fuels need in society. Fossil fuel is a non-renewable fuel.<br />Biofuel as an alternative fuel can be taken as a solution to solve this problem. The<br />reviewd aim was to determine the effect of raw materials used on yield product and<br />the different effects of temperature and catalysts on the yield of special materials<br />(gasoline, diesel, kerosene) biofuel. Biofuel production started from the<br />preparation of raw materials, catalylic, and catalytic cracking process using a<br />fixed bed reactor. Raw materials greatly affected yield product. The highest yield<br />products were being gotten from RBDPS raw materials of 93.29%. Biofuel from<br />used cooking oil and concentration of red sludge catalyst of 15% produced the<br />highest biofuel with gasoline compound of 73.86% and kerosene compound of<br />26.14%. Biofuel from camelina oil with ZSM-5-Zn catalyst concentration of 30%<br />produced the highest gasoline yield of 75.65%.</span></td></tr></tbody></table>

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Synthesis and catalytic performance of bimetallic NiMo- and NiW-ZSM-5/MCM-41 composites for production of liquid biofuels

Cited by 17 publications

References 26 publications

Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica

Selective Production of Green Hydrocarbons from the Hydrotreatment of Waste Coconut Oil over Ni- and NiMo-supported on Amine-functionalized Mesoporous Silica

Efficient Activation of Coal Fly Ash for Silica and Alumina Leaches and the Dependence of Pb(II) Removal Capacity on the Crystallization Conditions of Al-MCM-41

Proses Pembuatan Biofuel dengan Metode perengakahan Menggunakan Katalis Padat

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