Synthesis and Characterization of 3-Methoxypropyldithiocarbamate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and Their Adducts with Nitrogen Base Ligands

Al-Mukhtar, Saad E.; Aghwan, Marwa Th.

doi:10.33899/rjs.2013.77816

Cited by 4 publications

(2 citation statements)

References 21 publications

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“…The band at 1075 cm -1 due to υ(C-S) of the ligand which shifted to a lower frequency 995-1052 cm -1 (15).…”

Section: Ir Spectramentioning

confidence: 97%

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

AMEEN,

AHMED

2023

Journal of the Turkish Chemical Society Section A: Chemistry

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This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Ni(II), Cu(II), and Zn(II) and through the interaction with ligand (potassium decyl xanthate) and complexes of formula [M(DEXANT)2] were prepared: M= Ni(II), Cu(II), and Zn(II), and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula [M(DEXANT)2.L], where L= 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

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“…The band at 1075 cm -1 due to υ(C-S) of the ligand which shifted to a lower frequency 995-1052 cm -1 (15).…”

Section: Ir Spectramentioning

confidence: 97%

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

AMEEN,

AHMED

2023

Journal of the Turkish Chemical Society Section A: Chemistry

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“…This shift signified the coordination site originating from the atom of the nitrogen of azomethine group [14][15]. Additional bands emerged in all of the spectra, and they were assigned to the M-NTMP bond, thus showing the nitrogen atoms interacting in coordination with the metal ions [16].…”

Section: Infrared Spectroscopymentioning

confidence: 99%

New Series of Ni(II), Cu(II), Zr(IV), Ag(I), and Cd(II) Complexes of Trimethoprim and Diamine Ligands: Synthesis, Characterization, and Biological Studies

Al-Assafe,

Al-Quaba

2024

Indones. J. Chem.

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New compounds series of [M(TMP)(en)]X·nH2O and [M(TMP)(PD)]X·nH2O, where M = Ni2+, Cu2+, Zr4+, Ag+, Cd2+, TMP = trimethoprim, en = ethylenediamine, PD = o-phenylene and X= Cl− or NO3−, were prepared. The compounds were characterized using techniques including melting points, conductance, elemental analysis, FTIR, NMR, and mass spectroscopy. FTIR spectra indicated TMP acted like a bi-dentate ligand, combining via the nitrogen atoms of azomethine and pyrimidine amino groups. Diamine ligands (en or o-PD) are coordinated via two nitrogen atoms. Prepared compounds showed monomeric behavior and adopted a 6-coordinate octahedral geometry based on magnetic susceptibility and UV spectra. Conductivity measurements revealed Zr(IV) compounds were 1:2 conductive, while Ag+ and Cd2+ were 1:1 conductive; Ni2+ and Cu2+ compounds were non-conductive. Antibacterial tests on compounds and ligands against Bacillus subtilis and Staphylococcus aureus demonstrated broad-spectrum antibacterial activity. The mixed metal compounds revealed an observable tendency of antibacterial activity in the order Zr > Cd = Ag > Cu, making Zr(IV) compounds the most biologically active among them against S. aureus (Gram-positive) while the same compounds showed less antibacterial activity against B. subtilis (Gram-negative) than the free ligand.

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Synthesis, characterization, and biological evaluation of some metal complexes containing N and S donor atoms

Saiyed

Adeyemi

Singh

et al. 2023

Results in Chemistry

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Synthesis and Characterization of 3-Methoxypropyldithiocarbamate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and Their Adducts with Nitrogen Base Ligands

Cited by 4 publications

References 21 publications

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

New Series of Ni(II), Cu(II), Zr(IV), Ag(I), and Cd(II) Complexes of Trimethoprim and Diamine Ligands: Synthesis, Characterization, and Biological Studies

Synthesis, characterization, and biological evaluation of some metal complexes containing N and S donor atoms

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