Synthesis and characterization of alkylaluminum compounds of pentafluorothiophenol. Crystal and molecular structure of [Me2Al(.mu.-SC6F5)]2

Synthesis and Characterization of Aluminum and Gallium Complexes of Heterocyclic Carboxaldehyde Thiosemicarbazones. Single-Crystal Structure of [(MeAl){NC4H3CHNNC(S)NiC3H7}(AlMe2)]2and (GaMe2)2[SC4H3CHNNC(S)NPh]

“…The amido Al(1)−N(1) distance is slightly shorter than the imine Al(1)−N(8) bond (1.902(4) Å) and the other pyridyl Al−N bond, indicating that the negatively charged amido nitrogen atom is a stronger donor to the aluminum center than the neutral imine nitrogen atom. The Al(1)−S(10*) distance (2.326(2) Å) is comparable to that observed for the thiolate compound, AlH(SCH 2 CH 2 NEt 2 ) 2 (2.271(1) Å), the cubane compound, [( t Bu)Al(μ 3 -S)] 4 (2.316(9) Å), and the bridged sulfur compound, [AlMe 2 (μ-SC 6 F 5 )] 2 (2.405 Å) …”

“…As shown in Figure 1 (2.316(9) Å), 16 and the bridged sulfur compound, [AlMe 2 (µ-SC 6 F 5 )] 2 (2.405 Å). 17 The Al(1)-C(15) bond distance (1.944(6) The proximity of the amido nitrogen atom to the aluminum atom appears to be the reason for the asymmetric arrangement. The imine N(8)-C(9) bond distance (1.362(6) Å) is indicative of some double-bond character.…”

Cyclopentadienylaluminum thiolates – synthesis and structure

“…for C 8 3.45 (sept, 3 J = 6.6 Hz, 1H, CH), 6.24 (s, 5H, C 5 H 5 ); (CDCl 3 , d, ppm) 1.35 (d, 3 J = 6.6 Hz, 6H, CH 3 ), 3.46 (sept, 1H, CH), 6.26 (s, 5H, C 5 H 5 ). 13 (CH), 113.56 (C 5 H 5 ).…”

“…Among these compounds aluminum alkoxides have been the most systematically and broadly examined (see for example [2]). Comparing to aluminum alkoxides the chemistry of thiolate derivatives is rather scant [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17]. The structures of organoaluminum thiolates are diversified and the factors controlling them are not still definitely examined.…”

Chalcogenides of aluminium(III) and gallium(III) derived from Lewis base adducts of alane and gallane

“…The Al᎐(µ-Se) distances are uniform across the three complexes, 2.344( 2 52 It is also shorter than that in the four-co-ordinate dinuclear thiolato complex [{AlMe 2 -(µ-SC 6 F 5 )} 2 ], 2.405(8) Å. 53 The Al᎐Se (terminal) distance in trans-[{Al(µ-Se)(SePh)(NMe 3 )} 2 ] is significantly longer than the Al᎐Se distances in the Al 2 Se 2 core, but comparable with the upper limit observed in [Al(SePh) 3 (NMe 3 )], and is considerably shorter than that in the dinuclear complex [{Al(mes) 2 -(µ-SeMe)} 2 ], 2.519(2) Å. 8 The Al᎐Te (terminal) distance is slightly elongated compared to Al᎐Te in trans-[{AlH-(µ-Te)(NMe 3 )} 2 ], 2.586(4) and 2.580(4) Å, and [Al(TePh) 3 -(NMe 3 )], 2.581(2)-2.589(2) Å, but shorter than in [{AlBu t 2 -(µ-TeBu t )} 2 ], 2.732(3) Å.…”