2009
DOI: 10.1007/s10973-008-9045-8
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Synthesis and characterization of antimony trichloride and bismuth trichloride complexes with valine

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Cited by 8 publications
(3 citation statements)
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“…3 Report on synthesis and characterization of antimony and bismuth complexes of valine using a direct solid-solid reaction is also available in the literature. 4 On the other hand, ab initio studies have been carried out to characterize the gas-phase conformer of valine. 5 However, to the best of our knowledge, the literature survey reveals no reference on the utilization of a combined solid state experimental and quantum chemical investigation exploring the interactions of L-Val with the divalent metal ions of nickel, copper and zinc that can provide much deeper insights into the physicochemical properties of such metal complexes as well as the inuence of metal coordination on the structural aspects of L-Val.…”
Section: Introductionmentioning
confidence: 99%
“…3 Report on synthesis and characterization of antimony and bismuth complexes of valine using a direct solid-solid reaction is also available in the literature. 4 On the other hand, ab initio studies have been carried out to characterize the gas-phase conformer of valine. 5 However, to the best of our knowledge, the literature survey reveals no reference on the utilization of a combined solid state experimental and quantum chemical investigation exploring the interactions of L-Val with the divalent metal ions of nickel, copper and zinc that can provide much deeper insights into the physicochemical properties of such metal complexes as well as the inuence of metal coordination on the structural aspects of L-Val.…”
Section: Introductionmentioning
confidence: 99%
“…As our synthesized compounds are complexes, and due to the lone pair of electrons, distortion occurs due to which it undergoes lower symmetry, yet the characteristic and prominent peaks of complexes and the crystal system have been identified, which are equal and in some cases nearly match the standard diffraction card JCPDS 48–2458 and the literature 33–35. Along with these formulae, other information related to our synthesized complexes was collected from standard books 32…”
Section: Resultsmentioning
confidence: 99%
“…Therefore, to prepare the complexes of the arsenic and natural amino acids and to study the biologic activity of these complexes will be very interesting not only for the biologic chemistry of main group metal elements but also for the 2 Journal of Chemistry medicinal application of the amino acid complexes. Some amino acid or peptide complexes of antimony and bismuth have been synthesized by a direct solid-solid reaction [14][15][16][17]. Aspartic acid is one of the natural amino acids in the human body.…”
Section: Introductionmentioning
confidence: 99%