Synthesis and characterization of chiral (-)-menthyltin(IV) compounds. X-ray structure of tert-butyl-8-(dimethylamino)naphthyl-(-)-menthyltin hydride

Schumann, Herbert; Wassermann, Birgit C.; Hahn, F. Ekkehardt

doi:10.1021/om00044a019

Cited by 67 publications

(22 citation statements)

References 4 publications

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“…There have been several reports concerning potentially intramolecularly coordinated tin compounds, including hydrides in which the tin atom is coordinated to nitrogen [1][2][3][4][5][6][7][8] or phosphorus [9] from the ligand. We have recently described the synthesis and NMR study of tin hydrides 1-3 containing the chiral oxazoline moiety (Fig.…”

Section: Introductionmentioning

confidence: 99%

New chiral tin compounds containing the 2-(4-isopropyl-2-oxazolinyl)-5-phenyl ligand

Stalinski

Urbańczyk‐Lipkowska

Cmoch

et al. 2006

Journal of Organometallic Chemistry

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Section: Introductionmentioning

confidence: 99%

New chiral tin compounds containing the 2-(4-isopropyl-2-oxazolinyl)-5-phenyl ligand

Stalinski

Urbańczyk‐Lipkowska

Cmoch

et al. 2006

Journal of Organometallic Chemistry

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“…Na 2 MoO 4 AE2H 2 O was obtained from Aldrich and (-) -menthyldimethyltin bromide was synthesized as described in the literature [30]. Microanalyses were performed at the ITQB, Oeiras (by C. Almeida).…”

Section: Methodsmentioning

confidence: 99%

Characterization of a chiral menthyldimethyltin molybdate and its use as an olefin epoxidation catalyst

et al. 2007

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Vibrational spectroscopy and EXAFS studies of an organotin molybdate with the formula [((Me) 2 (menthyl)Sn) 2 MoO 4 (H 2 O) 3.5 ] reveal that the compound is polymeric and contains [MoO 4 ] 2) tetrahedra coordinated to [R 3 Sn] + cationic spacers. The compound can be used as a recyclable solid catalyst for the selective epoxidation of cyclooctene by tert-butylhydroperoxide. In the epoxidation of prochiral olefins such as trans-b-methylstyrene, the corresponding epoxide isomers are obtained with fairly good to excellent selectivity, albeit with low enantiomeric or diastereomeric excesses.

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“…To date, few chiral organolead compounds have been prepared 29 . The route outlined in Scheme 15 for the preparation of plumbane 55 is similar to the approach employed for the pentacoordinated organostannanes 47-54 described in the previous section.…”

Section: Leadmentioning

confidence: 99%

Stereochemistry and Conformation of Organogermanium, Organotin and Organolead Compounds

Marshall

Jablonowski

2009

Patai's Chemistry of Functional Groups

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Introduction Chiral Organometallics of Type R 1 R 2 R 3 R 4 M Germacyclopentanes and Cyclohexanes Organometallics of Type R * MR 3 Propargyl/Allenyl Systems

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Synthesis and characterization of chiral (-)-menthyltin(IV) compounds. X-ray structure of tert-butyl-8-(dimethylamino)naphthyl-(-)-menthyltin hydride

Cited by 67 publications

References 4 publications

New chiral tin compounds containing the 2-(4-isopropyl-2-oxazolinyl)-5-phenyl ligand

New chiral tin compounds containing the 2-(4-isopropyl-2-oxazolinyl)-5-phenyl ligand

Characterization of a chiral menthyldimethyltin molybdate and its use as an olefin epoxidation catalyst

Stereochemistry and Conformation of Organogermanium, Organotin and Organolead Compounds

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