Synthesis and characterization of graphene oxide‐based hybrid ligand and its metal complexes: Highly efficient sensor and catalytic properties

Karabörk, Muharrem; Zubair, Rizgar Maher; Uruş, Serhan; Tümer, Mehmet

doi:10.1002/aoc.4393

Cited by 8 publications

(3 citation statements)

References 26 publications

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“…In the case of Ni/GO/NiTAM, the sharp absorption band of carboxylate ions related to the GO-Ni-complex has appeared at 1625 cm −1 . In addition, the absorption band of 1382 cm ‒1 was become more intense, which corroborates the well-known complexation interaction between the metal and GO [ 41 ]. Such interaction between the Ni and GO groups has been led to the deposition of GO on the presented SPME fiber surface.…”

Section: Resultssupporting

confidence: 79%

Preparation of a new coating of graphene oxide/nickel complex on a nickelized metal surface for direct immersion solid phase microextraction of some polycyclic aromatic hydrocarbons

Pasandideh

Razmi

2021

BMC Chemistry

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Background Solid-phase microextraction (SPME) is a versatile sampling and sample preparation technology that possess a significant application in the extraction and pre-concentration of a broad range of micro-pollutants from different kind of matrices. Selection and preparation of an appropriate fiber substrate and coating materials have always been the main challenges of the SPME procedure. This paper introduces a high-efficiency metal-based SPME fiber with a new chemical coating of nickel/graphene oxide/nickel tetraazamacrocyclic complex (Ni/GO/NiTAM). Result The Ni/GO/NiTAM sorbent was electroless deposited onto the surface of an aluchrom (Alu) wire, and then the prepared fiber was employed for the extraction and pre-concentration of some PAHs before their HPLC–UV analysis. The prepared fiber characterization data were assessed using FE-SEM, EDX, XRD, FT-IR, and BET techniques. The method validation parameters, including the linearity range (LRs: 0.10 to 200.0 µg L−1), the limit of detection (LODs: 0.03‒0.30 µg L−1), and the limit of quantification (LOQs: 0.10–1.00 µg L−1), under optimal conditions. The relative standard deviations (RSDs) of intra-day, inter-day, and single fiber repeatability (for the samples spiked at 25 µg L‒1) were in the range of 0.32–2.94, 1.20–4.09, and 1.42‒4.39%, respectively. In addition, the technique recoveries (RR %) and enrichment factors (EF) were in the range of 83.10‒107.80% and 83–164, respectively. Conclusion The fiber fabrication was simple, and the applied materials were also economical and easily accessible. Alu metal has high physicochemical and mechanical stability and thus can be a good alternative for the substrate of the fragile commercial SPME fibers. High rigidity and durability, long service life, and high extraction capability are some of the other advantages of the offered fiber.

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Section: Resultssupporting

confidence: 79%

Preparation of a new coating of graphene oxide/nickel complex on a nickelized metal surface for direct immersion solid phase microextraction of some polycyclic aromatic hydrocarbons

Pasandideh

Razmi

2021

BMC Chemistry

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“…Since then, from the GO’s initial studies in biosensor applications based on fluorescence resonance energy transfer (FRET), it has gained continuous attention toward the detection of biomolecules such as DNA, RNA, peptides, ATP, and unfolded collagen fragments . Also, it expanded to the detection of small molecules such as cholesterol, glucose, biological cyanide, dopamine, and vitamin B 2 and was further elaborated to detect metal ions like Fe(II), Fe(III), Pb(II), Ag(I), Hg(II), Au(III), and fluoride anion . In the majority of studies, the PL response of GO was quenched by either grafted or physisorbed analytes and nanoparticles on the surface of the basal plane, which is inferred through blocking or unblocking of the GO surface .…”

Section: Introductionmentioning

confidence: 99%

Covalently Modified Graphene Oxide as Highly Fluorescent and Sustainable Carbonaceous Chemosensor for Selective Detection of Zirconium ion in Complete Aqueous Medium

Asha

Suresh

2020

ACS Sustainable Chem. Eng.

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Zirconium, a medically important transition metal, found extensive application and was found to be relatively safe, however, continuous exposure will lead to adverse effects. Though zirconium is considered as a safe metal in biomaterials, no reliable sensing methodologies have been developed. In the present report, for the detection of medically influential zirconium(IV) ions, a graphene-based carbonaceous material has been developed. Covalent modification of graphene oxide (GO) with 2-bis(pyridine-2-ylmethyl)amino)ethan-1-ol (PAE) provides a new material GOP which is characterized using various analytical techniques such as elemental analysis, energy dispersive spectroscopy (EDS), FTIR, PXRD, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and microscopic techniques SEM and HRTEM. All the analytical characterization techniques strongly supported the formation of covalently 2-bis(pyridine-2-ylmethyl)amino)ethan-1-ol tethered GO through an ester bond. Upon testing with a series of metal cations, intriguingly, an excellent photoluminescence response has been selectively originated from GOP with Zr(IV) in aqueous medium and it is utilized for the detection of Zr(IV). High selectivity toward Zr(IV) over the presence of other common coexisting metal ions was also demonstrated. Specific "turn-on" fluorescence response of GOP in the presence of Zr(IV) ion is rationalized via Fluorescence Resonance Energy Transfer (FRET) mechanism owing to the presence of ester bond as a spacer which brings PAE and GO closer. Further, the GOP is highly stable and sustainable, could recover and reuse for further sensor studies. The newly developed carbonaceous GOP material offers a new methodology for the detection of Zr(IV) in an aqueous medium with LOD of 27 ng/mL.

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“…Very few studies have been done for their applications in organic reactions as catalysts, whereas more attention was sought toward fuel cells, sensors, water purification, hydrogen storage, solar energy conversion, and solar cells. [ 77–80 ]…”

Section: Design Properties and Applications Of Metal‐supported Gomentioning

confidence: 99%

Recent advancements in organic synthesis catalyzed by graphene oxide metal composites as heterogeneous nanocatalysts

Soni¹,

Sethiya²,

Sahiba³

et al. 2021

Applied Organom Chemis

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In the last decades, heterogeneous catalysis has emerged as a promising approach for sustainable synthesis. Among this, metal‐based graphene oxide (GO) as catalysts is widely used due to their unique properties such as physical and thermal stability of the catalysts in successive reaction runs and reusability. Metal‐supported GOs are quite prevalent and probably suitable acidic catalysts for both research laboratories and industrial processes. Herein, we have described the catalytic efficiency of various metal‐supported GO catalysts in different organic transformations like oxidation, reduction, multicomponent reactions, alkylation, condensation, dehydration, dehydrogenation, and Suzuki, Heck, and Sonogashira reactions. This article has been divided into three subsections: (i) GO‐supported metal as a catalyst, (ii) GO‐supported bimetal as a catalyst, and (iii) GO‐supported metal oxide as a catalyst for the easier understanding of the vast community of researchers. The foremost aim of this article is to summarize the uses of metal‐supported GO in the preparation of diverse synthetic molecules. The recent advancements in GO metal composites as catalysts with their applications have been deliberated.

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Synthesis and characterization of graphene oxide‐based hybrid ligand and its metal complexes: Highly efficient sensor and catalytic properties

Cited by 8 publications

References 26 publications

Preparation of a new coating of graphene oxide/nickel complex on a nickelized metal surface for direct immersion solid phase microextraction of some polycyclic aromatic hydrocarbons

Preparation of a new coating of graphene oxide/nickel complex on a nickelized metal surface for direct immersion solid phase microextraction of some polycyclic aromatic hydrocarbons

Covalently Modified Graphene Oxide as Highly Fluorescent and Sustainable Carbonaceous Chemosensor for Selective Detection of Zirconium ion in Complete Aqueous Medium

Recent advancements in organic synthesis catalyzed by graphene oxide metal composites as heterogeneous nanocatalysts

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