Synthesis and crystal structure of Sm2MnTiO6

Neutron structural characterization and transport properties of oxidized and reduced La0.5Sr0.5M0.5Ti0.5O3 (M = Mn, Fe) perovskites: Possible electrode materials in solid-oxide fuel cells

“…12 It is also possible to form ALaMTiO 6 , where A is an alkaline earth or their solid solution and the ionic states of M and Ti are trivalent and tetravalent. 13 For M ¼ Mn, previous studies of Alvarez-Serrano et al have reported 50% substitution of Mn ions for Ti in Sr 0.5 La 0.5 MnO 3 .…”

Synthesis, structure analysis and magnetic properties of Ca2TiMnO6 oxides

“…A-sites are occupied by alkaline earth ions, and B'-sites and B''-sites correspond to different transition metal ions respectively [3][4][5][6][7][8]. Recently, series A 2 TiMnO 6 -type oxides are synthesized to investigate its structure and magnetoelectric coupling behaviours [9][10][11][12].…”

Nano‐Domain Twin Structure Formed by Phase Transition in New Perovskite Oxide (Sr0.67Sm0.33)(Mn0.33Ti0.67)O3

“…Oxides with a combination of Mn and Ti ions at the B sites were synthesized under various atmospheres by varying the oxidation states of these ions. The Ln 2 MnTiO 6 (Ln=rare earth) phase was synthesized in a reducing atmosphere, and it has an orthorhombic structure ( Pnma ) for Ln=La–Nd, a monoclinic structure for Ln=Sm–Gd, and a hexagonal structure ( P 6 3 cm ) for Yb 8–12 . Some of these oxides exhibit antiferromagnetic properties 9–11 .…”

“…The Ln 2 MnTiO 6 (Ln=rare earth) phase was synthesized in a reducing atmosphere, and it has an orthorhombic structure ( Pnma ) for Ln=La–Nd, a monoclinic structure for Ln=Sm–Gd, and a hexagonal structure ( P 6 3 cm ) for Yb 8–12 . Some of these oxides exhibit antiferromagnetic properties 9–11 . The oxide (Ca 0.9 La 0.1 )(Mn 1− x Ti x )O 3 was synthesized in a previous study with an orthorhombic structure ( Pnma ) in an oxygen gas flow 13 .…”