Synthesis and electropolymerisation of pyrrol-1-yl substituted phthalocyanines

Trombach, N.; Hild, Olaf R.; Schlettwein, Derck; Wöhrle, Dieter

doi:10.1039/b109283a

Cited by 53 publications

(28 citation statements)

References 19 publications

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“…Tetrasulfonated substituted complexes [238][239][240][241][242][243][244][245] have been introduced into polypyrrole films as counter-ions (or "doping" ions). Only few examples have described the electropolymerization of pyrrolesubstituted MPcs [246][247][248]. Most studies of polymeric MPcs have involved the electrochemical polymerization of tetraaminophthalocyanines (4␤(NH 2 )MPc) [77,119,137,230,[249][250][251][252][253][254][255] which involves the oxidation of the amino group to form radicals that initiate condensation by attacking phenyl rings of neighboring molecules.…”

Section: Metallophthalocyanine-based Molecular Electrodesmentioning

confidence: 99%

Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions

Zagal¹,

Griveau²,

Silva³

et al. 2010

Coordination Chemistry Reviews

548

415

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Section: Metallophthalocyanine-based Molecular Electrodesmentioning

confidence: 99%

Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions

Zagal¹,

Griveau²,

Silva³

et al. 2010

Coordination Chemistry Reviews

548

415

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“…47 The technique Recently, the synthesis and electropolymerization of two tetrakis(2-pyrrol-1-ylalkoxy)phthalocyanines has been reported, and the electrical and optical properties discussed. 48 This is the first example of the electropolymerization of a phthalocyanine where the electropolymerizable group (pyrrole) is electronically isolated from the phthalocyanine.…”

Section: Figurementioning

confidence: 99%

Electrochromic organic and polymeric materials for display applications

2006

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An electrochromic material is one where a reversible color change takes place upon reduction (gain of electrons) or oxidation (loss of electrons), on passage of electrical current after the application of an appropriate electrode potential. In this review the general field of electrochromism is introduced, with coverage of the types, applications, and chemical classes of electrochromic materials and the experimental methods that are used in their study. The main classes of electrochromic organic and polymeric materials are then surveyed, with descriptions of representative examples based on transition metal coordination complexes, viologen systems, and conducting polymers. Examples of the application of such organic and polymeric electrochromic materials in electrochromic displays are given.

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“…Immobilization of MPcs on electrodes by polymerization or by the formation of self-assembled monolayers results in reproducible thin films. However, their formation requires the synthesis of ring substituted MPc complexes, which is very time consuming [17][18][19]. Methods for electrode modification using readily available MPc complexes are thus being developed.…”

Section: Introductionmentioning

confidence: 99%