Synthesis and Liquid Crystalline Behavior of Random Copolymer of Poly(ethylene oxide) Macromonomer and Liquid Crystalline Monomer by the Photon Transmission Technique

Abstract

Random copolymers of poly(ethylene oxide) macromonomer with p-vinylbenzyl end-functional group (PEOVB) and liquid crystalline monomer, namely 6-(4-cyanobiphenyl-4 0 -oxy)hexyl acrylate (COA), were prepared by conventional free radical polymerization. A living anionic polymerization technique was employed for the synthesis of PEO macromonomers bearing p-vinylbenzyl moiety at one end. The photon transmission method was also applied to study the phase transitions of COA monomer and its random copolymer with PEO. It was found that, for both samples, the nematic-smectic A transition is continuous, but the critical fluctuation regions do not allow to obtain 3D XY values. Instead, we have obtained the values close to mean field regime. Scaling of thermal hystersis for random copolymer sample near the nematic-isotropic transition was studied as well. Thermal hysteresis loops were produced under linearly varying temperature. It was shown that the areas of the hysteresis loops scale with the temperature scanning rate with an exponent being equal to 0.614 which is in good agreement with the field-theoretical value.

Synthesis of Poly(isobutyl vinyl ether)-graft-Poly(ethylene oxide) Co-polymer with Pendant Methacrylate Functionality and Its Photo-curing Behavior

“…After the block formation, PVEC block can readily be crosslinked by photochemical means by intermolecular dimerization of the cinnamate groups (Scheme 1). We have recently described a new synthetic strategy for the preparation of heterofunctional macromonomers carrying methacryloyl group at one end, and dimethyl amino, thiophene, styryl and vinyl ether functional groups at the other end [13][14][15][16][17][18][19]. In this strategy, first anionic polymerization of ethylene oxide (EO) was initiated with functional potassium alcoholates, and then living ends were reacted with methacryloyl chloride.…”

“…In this strategy, first anionic polymerization of ethylene oxide (EO) was initiated with functional potassium alcoholates, and then living ends were reacted with methacryloyl chloride. These macromonomers were further utilized in various macromolecular architectures via concurrent or selective thermal free radical [19,20], oxidative [15] and photoinitiated free radical [13,21,22] and cationic polymerization [21] methods. It was also shown that graft co-polymers with completely and perfectly alternating hydrophilic side-chains can be prepared by charge-transfer-polymerization of the styrene functional macromonomers with phenyl maleimide [20].…”