Abstract:A series of (Y1−y, Gdy)0.95−x(Py, V1−y)O4:0.05Eu 3+ , xBi 3+ phosphors have been successfully prepared by a subsection method. The crystal structure, surface morphology and luminescence properties were investigated. It was found that the sintered samples crystallized in a tetragonal crystal system with space group I41/amd(a = b = 0.7119 nm, c = 0.6290 nm). The products presented rod-like morphology with length of 100-150 nm and width of 50-100 nm. A maximum peak at 619 nm ( 5 D0 → 7 F2) was observed in emission spectrum of the phosphors. It was also found that co-doping of Bi 3+ , P 5+ and Gd 3+ ions into YVO4:Eu 3+ can not only made the right edge of the excitation band shift to the long-wavelength region, but also increased the emission intensity at 619 nm sharply and decreased the lifetime of fluorescence decay. These results may expand the application scope of the phosphors.